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The anodic passivation of lithium
Journal of Power Sources, 1983The anodic passivation of Li has been characterized at room temperature in a variety of electrolytes (propylene carbonate, thionyl chloride, sulfur dioxide), as a function of convection and current density and in the presence of water and other impurities.
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Lithium anode for lithium-air secondary batteries
Journal of Power Sources, 2008Abstract The lithium ion conducting solid lithium phosphorous nitride (LiPON) has been sputtered on the water-stable NASICON-type lithium ion conducting solid electrolyte Li 1+ x + y Al x Ti 2− x P 3− y Si y O 12 (LATP). The stability and the interface resistance of the Li–Al/LiPON/LATP/LiPON/Li–Al cell have been examined.
Nobuyuki Imanishi +5 more
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Lithium-Anode Protection in Lithium–Sulfur Batteries
Trends in Chemistry, 2019Lithium–sulfur (Li–S) batteries show significant promise as next-generation energy-storage devices due to their high energy density (2600 Wh kg-1). However, the severe shuttling of polysulfide intermediates and low Coulombic efficiency during operation induce rapid capacity loss, hindering their practical applications.
Chong Yan +4 more
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Kinetic understanding of lithium metal electrodeposition for lithium anodes
Physical Chemistry Chemical PhysicsA comprehensive understanding of the kinetic impacts on lithium deposition and growth is outlined, along with a discussion of diverse strategies for kinetic control and regulation of lithium deposition behaviors.
Rong Fang +4 more
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Fluorescence Probing of Active Lithium Distribution in Lithium Metal Anodes
Angewandte Chemie International Edition, 2019AbstractThe uncontrollable growth of Li dendrites and the accumulation of byproducts are two severe concerns for lithium metal batteries, which leads to safety hazards and a low Coulombic efficiency. To investigate the deterioration of the cell, it is important to figure out the distribution of active Li species on the anode surface and distinguish Li ...
Xiangyang Cheng +8 more
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Key Aspects of Lithium Metal Anodes for Lithium Metal Batteries
Small, 2019AbstractRechargeable batteries are considered promising replacements for environmentally hazardous fossil fuel‐based energy technologies. High‐energy lithium‐metal batteries have received tremendous attention for use in portable electronic devices and electric vehicles.
Zahid Ali Ghazi +6 more
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3D-hosted lithium metal anodes
Chemical Society ReviewsThis review is organized based on the historical progress, classification, regulating mechanism of scaffolds/hosts for Li metal anodes, and their future design criteria.
Xin He +4 more
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Interphase Design for Lithium-Metal Anodes
Journal of the American Chemical SocietyElectrode-electrolyte interphases are critical determinants of the reversibility and longevity of lithium (Li)-metal batteries (LMBs). However, upon cycling, the inherently delicate interphases, formed from electrolyte decomposition, become vulnerable to chemomechanical degradation and corrosion, resulting in rapid capacity loss and thus short battery ...
Qidi Wang +12 more
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ECS Meeting Abstracts, 2019
Over the last several decades, new battery technologies have been developed due to the need for consistently high energy density batteries. Lithium metal is the ideal cathode for next-generation lithium batteries, because it has a high specific capacity (3860 mAh g−1) and the lowest reduction potential (−3.040 V vs. standard hydrogen electrode, SHE).
Nak Gyu Go +2 more
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Over the last several decades, new battery technologies have been developed due to the need for consistently high energy density batteries. Lithium metal is the ideal cathode for next-generation lithium batteries, because it has a high specific capacity (3860 mAh g−1) and the lowest reduction potential (−3.040 V vs. standard hydrogen electrode, SHE).
Nak Gyu Go +2 more
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Interface Modifications of Lithium Metal Anode for Lithium Metal Batteries
ChemSusChemAbstractLithium metal batteries (LMBs) enable much higher energy density than lithium‐ion batteries (LIBs) and thus hold great promise for future transportation electrification. However, the adoption of lithium metal (Li) as an anode poses serious concerns about cell safety and performance, which has been hindering LMBs from commercialization.
Ramesh Kumar Petla +3 more
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