Stereochemical Control in the Matteson Reaction
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley +1 more source
To fully leverage the power of the ruthenium‐catalyzed trans‐hydrosilylation of propargyl alcohols, it was necessary to develop a practical and robust method for the activation of those products that carry the silyl group distal to the hydroxy substituent.
Paul Haf‐Moths +2 more
wiley +2 more sources
Stereodivergent Synthesis of C5-α-Substituted Linezolid Derivatives From D-Mannitol and Structure-Antibacterial Activity Evaluation. [PDF]
Gálvez JA +3 more
europepmc +1 more source
Room-Temperature Oxidative Cyclization of Carboxylic Acids Promoted by Copper(II) Trifluoromethanesulfonate and Selectfluor. [PDF]
Sathyamoorthi S.
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Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
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Stereocontrolled Synthesis of Polysubstituted Housanes via <i>gem</i>-Bismetalated Cyclopropanes. [PDF]
Orbach N, Suresh R, Marek I.
europepmc +1 more source
Deprotonation-mediated vitrification of organic-inorganic hybrid perovskites. [PDF]
Wang P +13 more
europepmc +1 more source
Halide-Based Solid Electrolytes for Advanced All-Solid-State Batteries: Design, Interfaces, and Electrochemical Performance. [PDF]
Guddehalli Chandrappa S +2 more
europepmc +1 more source
Environmental Impacts of Perovskite Solar Cell Materials: Transparency and Reproducibility Gaps, and Reporting Recommendations. [PDF]
Kamali AK +3 more
europepmc +1 more source
A library of 21 tetrakis(phenothiazinyl)‐substituted silanes with broadly variable substituent decoration, which are fully reversible multistage redox systems with intense tunable emission from deep blue to yellow–green (441–533 nm), was rapidly synthesized by bromine–lithium exchange/borylation–Suzuki coupling of tetrakis(4‐bromophenyl)silane or by ...
Thomas P. M. Merke +4 more
wiley +1 more source

