Hotspot to Homogeneous: Amorphous Interfacial Current Redistribution Enables Stable Solid-State Lithium-Metal Batteries. [PDF]
Yang C +10 more
europepmc +1 more source
Breaking the Polarity–Coordination Coupling in Electrolyte Design for High‐Voltage Lithium Batteries
Steric and electronic co‐regulation of 2,2,2‐trifluoro‐N, N‐dimethylethylamide (DMTFA) decouples high polarity from strong Li+ coordination, creating an anion‐mediated pseudo‐weakly solvating electrolyte. This design lowers Li+ desolvation barriers, enhances Li+ mobility, and builds B‐, F‐, and N‐rich inorganic interphases, enabling stable 3.0–4.6 V ...
Xue Li +9 more
wiley +1 more source
Unveiling and regulating heterogeneous Li<sup>+</sup> transport in 3D scaffolds: a gradient electrodeposition strategy toward ultralight and stable Li metal anodes. [PDF]
Wang J +10 more
europepmc +1 more source
Bio‐based gel polymer electrolytes promise sustainable, mechanically adaptable zinc–air batteries, yet their progress is constrained by inconsistent characterization. This review critically links formulation, structure, interfaces, and cell performance, identifies methodological gaps under alkaline operating conditions, and proposes application ...
Matteo Milanesi +6 more
wiley +1 more source
Local electrostatic field achieved by charge redistribution for stable solid-state lithium metal batteries. [PDF]
Mao P +14 more
europepmc +1 more source
The application of a generative diffusion model, enhanced with a training data augmentation pipeline retaining the manufacturing process context of electrode microstructures, leads to improved fidelity of the through‐plane tortuosity factor in the AI generated samples.
Victor Ramirez‐Camacho +5 more
wiley +1 more source
Lithium Surface Restructuring and Dendrite-Like Protrusion Formation in Li-S Electrolytes From Reactive Molecular Simulations With Machine-Learned Potentials. [PDF]
Maahury MF +7 more
europepmc +1 more source
Fluorine‐containing electrolytes dominate modern rechargeable batteries, yet the fundamental design principles for fluorine‐free systems remain largely unexplored. We demonstrate that fluorine‐free electrolyte chemistry can simultaneously achieve long cycle life, fast charging, and stable interphase formation in sodium‐ion batteries.
Dawei Xia +7 more
wiley +1 more source
To regulate a distinct degradation pathway introduced by residual monomers in in‐situ gel polymer electrolytes (GPEs), tris(4‐fluorophenyl)phosphine (TFPP) is coupled with a voltage hold (VH) protocol. TFPP first covers the high‐Ni cathode surface and then preferentially decomposes during the hold step, forming a cathode–electrolyte interphase (CEI ...
Sang Goo Kang +4 more
wiley +2 more sources
Reveal Non‐Uniform Passivation on Lithium Metal Anode With Operando Spectroscopic Ellipsometry
In‐operando spectroscopic ellipsometry reveals how nucleation and crystallographic orientation govern the non‐uniform growth of native passivation films on lithium metal. Time‐resolved thickness mapping captures island formation and coalescence, while orientation‐dependent measurements show that the equilibrium film on Li(110) is approximately half as ...
Jianyu Li +3 more
wiley +1 more source

