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Scalable Upcycling of Spent Lithium‐Ion Battery Anodic Graphite to Electronic‐Grade Graphene
Graphite anodes from spent lithium‐ion batteries are upcycled into electronic‐grade graphene nanoplatelets for highly conductive screen printing inks (> 104 S m−1). Screen‐printed micro‐supercapacitors confirm the utility of the upcycled graphene (1.78 mF/cm2 capacitance for > 10 000 cycles). Life cycle assessment and techno‐economic analysis highlight
Janan Hui +8 more
wiley +1 more source
To inhibit electrolyte decomposition by nucleophilic attack in carbonate electrolyte, LiBOB and LiDFOP with strong oxygen scavenging ability are selected to quench reactive oxygen species and following construct a robust CEI film on the LRLO cathode. The electrochemical performance of the LRLO cathode is largely improved, attributed to decomposition ...
Jiahe Chen +9 more
wiley +1 more source
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Lithium Metal Anodes with Nonaqueous Electrolytes
Chemical Reviews, 2020High-energy rechargeable lithium (Li) metal batteries (LMBs) with Li metal anode (LMA) were first developed in the 1970s, but their practical applications have been hindered by the safety and low-efficiency concerns related to LMA. Recently, a worldwide effort on LMA-based rechargeable LMBs has been revived to replace graphite-based, Li-ion batteries ...
Ji-Guang Zhang, Wu Xu, Jie Xiao
exaly +3 more sources
Towards practical lithium-metal anodes
Chemical Society Reviews, 2020Lithium ion batteries cannot meet the ever increasing demands of human society. Thus batteries with Li-metal anodes are eyed to revive. Here we summarize the recent progress in developing practical Li-metal anodes for various Li-based batteries.
Xin Zhang, Yongan Yang, Zhen Zhou
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2021
Deposition and dissolution of lithium metal have been investigated in an equimolar mixture of lithium bis(trifluoromethylsulfonyl)amide (LiTFSA) and glyme [triglyme (G3) or tetraglyme (G4)] solvate ionic liquid. The limiting current for deposition of lithium was not observed probably because of the high concentration of lithium species and a decrease ...
Naoki Tachikawa +2 more
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Deposition and dissolution of lithium metal have been investigated in an equimolar mixture of lithium bis(trifluoromethylsulfonyl)amide (LiTFSA) and glyme [triglyme (G3) or tetraglyme (G4)] solvate ionic liquid. The limiting current for deposition of lithium was not observed probably because of the high concentration of lithium species and a decrease ...
Naoki Tachikawa +2 more
openaire +1 more source
Angewandte Chemie, 2017
AbstractThe rechargeable lithium metal anode is of utmost importance for high‐energy‐density batteries. Regulating the deposition/dissolution characteristics of Li metal is critical in both fundamental researches and practical applications. In contrast to gray Li deposits featured with dendritic and mossy morphologies, columnar and uniform Li is herein
Xue‐Qiang Zhang +7 more
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AbstractThe rechargeable lithium metal anode is of utmost importance for high‐energy‐density batteries. Regulating the deposition/dissolution characteristics of Li metal is critical in both fundamental researches and practical applications. In contrast to gray Li deposits featured with dendritic and mossy morphologies, columnar and uniform Li is herein
Xue‐Qiang Zhang +7 more
openaire +2 more sources
Lithium Host:Advanced architecture components for lithium metal anode
Energy Storage Materials, 2021Abstract With the increasing demand for high energy and power energy storage devices, lithium metal batteries have received widespread attention. Li metal has long been regarded as an ideal candidate for negative electrode due to its high theoretical specific capacity (3860 mAh g−1) and low redox potential (-3.04 V vs.
Yifeng Cheng +6 more
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Key Aspects of Lithium Metal Anodes for Lithium Metal Batteries
Small, 2019AbstractRechargeable batteries are considered promising replacements for environmentally hazardous fossil fuel‐based energy technologies. High‐energy lithium‐metal batteries have received tremendous attention for use in portable electronic devices and electric vehicles.
Zahid Ali Ghazi +6 more
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Controlling Nucleation in Lithium Metal Anodes
Small, 2018AbstractRechargeable batteries are regarded as the most promising candidates for practical applications in portable electronic devices and electric vehicles. In recent decades, lithium metal batteries (LMBs) have been extensively studied due to their ultrahigh energy densities.
Xuze Guan +7 more
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Stable Lithium Metal Anodes for Rechargeable Lithium Metal Batteries
ECS Meeting Abstracts, 2016Li metal is an ideal anode material for next-generation energy storage devices due to its extremely high theoretical specific capacity and the lowest negative electrochemical potential [1,2]. However, uncontrolled Li dendrite growth and the side reaction between Li metal and electrolytes have prevented its practical application in rechargeable Li ...
Nian-Wu Li +3 more
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