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We develop vacancy‐rich Co9S6.29 precatalysts formed via ultrafine MnS‐induced lattice distortion in mesoporous S‐doped N‐rich hollow carbon nanotubes (CM@SNHCTs). This CM@SNHCT precatalyst is reconstructed into catalytically‐active cathode phases that enable efficient oxygen reduction/evolution reactions (ORR/OER) through dynamic O‐vacancy formation ...
Debarani Devi Khumujam +10 more
wiley +1 more source
High‐entropy doping of Co‐free Ni‐rich LiNiO2 cathodes is achieved through a scalable 3D mixing process. Multi‐element incorporation stabilizes the layered structure, alleviates Li/Ni disorder and electrode swelling, and enhances cycling stability. This approach underscores the potential of high‐entropy strategies to deliver structurally robust and ...
Seung Ri Kim +6 more
wiley +1 more source
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Lithium Nitrate Regulated Sulfone Electrolytes for Lithium Metal Batteries
Angewandte Chemie - International Edition, 2020AbstractThe electrolytes in lithium metal batteries have to be compatible with both lithium metal anodes and high voltage cathodes, and can be regulated by manipulating the solvation structure. Herein, to enhance the electrolyte stability, lithium nitrate (LiNO3) and 1,1,2,2‐tetrafuoroethyl‐2′,2′,2′‐trifuoroethyl(HFE) are introduced into the high ...
Jiale Fu, Xiao Ji, Ji Chen
exaly +3 more sources
Challenges and progresses of lithium-metal batteries
Chemical Engineering Journal, 2021Abstract Lithium-metal batteries (LMBs) have received considerable enthusiasm as the candidates for next-generation high energy density storage devices. However, the unexpected electrochemical deposition of metallic Li on the surface of anode has been considered as the major obstacle, severely limiting the practical applications of high-performance ...
Wang, Jinming +8 more
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Click Chemistry in Lithium‐Metal Batteries
Small, 2023AbstractLithium‐metal batteries (LMBs) are considered the “holy grail” of the next‐generation energy storage systems, and solid‐state electrolytes (SSEs) are a kind of critical component assembled in LMBs. However, as one of the most important branches of SSEs, polymer‐based electrolytes (PEs) possess several native drawbacks including insufficient ...
Ji Hu +5 more
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Key Aspects of Lithium Metal Anodes for Lithium Metal Batteries
Small, 2019AbstractRechargeable batteries are considered promising replacements for environmentally hazardous fossil fuel‐based energy technologies. High‐energy lithium‐metal batteries have received tremendous attention for use in portable electronic devices and electric vehicles.
Zahid Ali Ghazi +6 more
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Electrolytes for Lithium‐ and Sodium‐Metal Batteries
Chemistry – An Asian Journal, 2020AbstractHigh‐energy‐density batteries have attracted significant attention due to the huge demand in electric transportation in future. Metal‐based batteries, especially lithium metal batteries (LMBs) and sodium metal batteries (SMBs), have been hot research topics nowadays.
Chenxuan Xu +9 more
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Lithium Foam for Deep Cycling Lithium Metal Batteries
Small, 2023AbstractLi metal anode has been recognized as the most promising anode for its high theoretical capacity and low reduction potential. But its large‐scale commercialization is hampered because of the infinite volume expansion, severe side reactions, and uncontrollable dendrite formation.
Aoxuan Wang +7 more
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Lithium Redistribution in Lithium-Metal Batteries
Journal of The Electrochemical Society, 2012A model of a lithium-metal battery with a CoO2 positive electrode has been modeled in order to predict the movement of lithium in the negative electrode along the negative electrode/separator interface during cell cycling. A finite-element approach was used to incorporate an intercalation positive electrode using superposition, electrode tabbing ...
Anthony Ferrese +3 more
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Lithium Redistribution in Lithium-Metal Batteries
ECS Meeting Abstracts, 2011Abstract not Available.
Anthony Ferrese, John Newman
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