Results 31 to 40 of about 2,092 (245)

Thiokol with Excellent Restriction on the Shuttle Effect in Lithium–Sulfur Batteries

Applied Sciences, 2018
Commercial application of lithium–sulfur (Li–S) batteries is still greatly hampered by several issues, especially the shuttle effect of polysulfides.
Bin Liu, Shan Wang, Quanling Yang, Guo-Hua Hu, Chuanxi Xiong   +4 more
doaj   +1 more source

Atomically Dispersed Ni Site Catalysts Accelerating Sluggish Sulfur Redox Kinetics in Nonaqueous Zn‐S Batteries

Advanced Functional Materials, EarlyView.
An atomically dispersed Ni catalyst featuring Ni‐N4 coordination is developed as a sulfur host for nonaqueous Zn─S batteries. This configuration modulates the electronic structure to lower activation barriers during rate‐limiting steps and promotes a robust ZnF2‐rich cathode‐electrolyte interphase, thereby accelerating sulfur redox kinetics ...
Junhyuk Ji, Dongwoo Kim, Nuri Moon, Daehwan Kim, Keon Kim, Nahyung Kim, Young Yong Kim, Won Bae Kim   +7 more
wiley   +1 more source

Construction of Electrocatalytic and Heat-Resistant Self-Supporting Electrodes for High-Performance Lithium–Sulfur Batteries

Nano-Micro Letters, 2019
Boosting the utilization efficiency of sulfur electrodes and suppressing the “shuttle effect” of intermediate polysulfides remain the critical challenge for high-performance lithium–sulfur batteries (LSBs). However, most of reported sulfur electrodes are
Xuemei Zhang, Yunhong Wei, Boya Wang, Mei Wang, Yun Zhang, Qian Wang, Hao Wu   +6 more
doaj   +1 more source

Charge‐Tunable Coacervate Micelles for Separator Engineering in Lithium‐Sulfur Batteries

Advanced Functional Materials, EarlyView.
A separator engineering strategy based on charge‐tunable complex coacervate core micelles (C3Ms) is presented to form an ion‐selective layer regulating polysulfide transport in Li–S batteries. The micelles enable uniform adsorption onto commercial polypropylene separators and infiltration throughout the internal pore network, suppressing polysulfide ...
Yongsheng Zhang, J. R. Andrade Aguirre, Julien Es Sayed, Chongyang Jiang, Yuxuan Zhang, Xiaolong He, Yinyu Xiang, Yutao Pei, Xiangping Zhang, Petra Ruldolf, Marleen Kamperman, Giuseppe Portale   +11 more
wiley   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

Advanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen, Zhanxi Fan, Jingjie Ge, Qiyuan He, Zhuangchai Lai, Jiawei Liu, Chaoliang Tan, Hua Zhang   +7 more
wiley   +1 more source

Review of Inorganic Separator Engineering for Next‐Generation Lithium–Sulfur Batteries: Compromise or Cornerstone?

Advanced Materials, EarlyView.
Inorganic compound‐modified separators transform lithium–sulfur batteries from passive polysulfide confinement to active reaction‐pathway regulation. A Practical Relevance Index (PRI)‐guided framework bridges interfacial chemistry of inorganic separators with practical constraints, establishing unified design principles for scalable, high‐energy ...
Yuting Qin, Tianyi Wang, Xingyu Wang, Kaifu Xu, Yuzhou Wang, Chengyin Wang, Bing Sun, Guoxiu Wang   +7 more
wiley   +1 more source

Lithium Polysulfide Interaction with Group III Atoms-Doped Graphene: A Computational Insight

Batteries, 2020
The development of long lifetime Li–S batteries requires new sulfur–carbon based composite materials that are able to suppress the shuttle effect—namely, the migration of soluble lithium polysulfides from the cathode to the anode of the cell. Graphene is
Mauro Francesco Sgroi, Daniele Pullini, Alina Iuliana Pruna   +2 more
doaj   +1 more source

Interfacial Failure and Self‐Healing in Solid‐State Batteries

Advanced Materials, EarlyView.
Dynamic interfacial self‐healing offers an adaptive route to mitigate coupled mechanical, chemical, and electrochemical degradation in solid‐state batteries. This review connects evolving interfacial failure mechanisms with physical‐flow, chemical‐restoration, stimuli‐responsive, and electric‐field‐assisted repair strategies, highlighting targeted self‐
Xinxin Zhu, Tengfei Dai, Wendi Dou, Zhiheng Li, Kaihua Wen, Yanqun Lv, Ming Zhao, Jun Lu, Zaiping Guo   +8 more
wiley   +1 more source

First-Principles Investigation of Phosphorus-Doped Graphitic Carbon Nitride as Anchoring Material for the Lithium-Sulfur Battery

Molecules
The utilization of lithium–sulfur battery is hindered by various challenges, including the “shuttle effect”, limited sulfur utilization, and the sluggish conversion kinetics of lithium polysulfides (LiPSs).
Yuehui Chen, Fengxia Liu, Shuang Wei, Yingkai Xia, Xiaodong Li, Shengnan Liu, Xu Zhang, Shuwei Tang, Ding Shen, Wei Dong, Shaobin Yang   +10 more
doaj   +1 more source

Synthesis and electrochemical performance of Mn₂O₃/Fe₂O₃/few layers graphene/ sulfur cathode for lithium-sulfur batteries

Cailiao gongcheng, 2020
Mn2O3/Fe2O3/few layer graphene/sulfur composites were prepared by melted salt method, interlayer catalytic exfoliation, annealing and melt diffusion method in sequence for lithium-sulfur batteries cathode.
WANG Nan, QI Xin, PENG Si-kan, CHEN Xiang, WANG Chen, DAI Sheng-long, YAN Shao-jiu   +6 more
doaj   +1 more source