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Polymerization in living organisms

Chemical Society Reviews, 2023
This review summarizes the progress of polymerization in living organisms. Based on different biological or cellular characteristics, versatile polymerization processes are designed and their corresponding therapeutic mechanisms are discussed.
Dan Wu   +5 more
openaire   +2 more sources

Oxidative Polymerization in Living Cells

Journal of the American Chemical Society, 2021
Intracellular polymerization is an emerging technique that can potentially modulate cell behavior, but remains challenging because of the complexity of the cellular environment. Herein, taking advantage of the chemical properties of organotellurides and the intracellular redox environment, we develop a novel oxidative polymerization reaction that can ...
Yiheng Dai   +6 more
openaire   +2 more sources

Photocontrolled living polymerizations

Nature Materials, 2006
Living polymerizations involve the creation of polymer chains without significant irreversible chain transfer or chain termination. Such processes are widely used to access well-defined macromolecular materials with controlled architectures, such as block and star polymers.
Makoto Tanabe   +6 more
openaire   +3 more sources

Living carbocationic polymerization. IV. Living polymerization of isobutylene

Journal of Polymer Science Part A: Polymer Chemistry, 1987
AbstractTruly living polymerization of isobutylene (IB) has been achieved for the first time by the use of new initiating systems comprising organic acetate‐BCl3 complexes under conventional laboratory conditions in various solvents from −10 to −50°C.
R. Faust, J. P. Kennedy
openaire   +1 more source

Living carbocationic polymerization. 55. Living polymerization of indene

Macromolecules, 1993
The cationic polymerization of indene (In) has been investigated using the 2-chloro-2,4,4- trimethylpentane (TMPCl)/TiCl 4 initiating system and a methyl chloride-methylcyclohexane solvent mixture at -80°C. According to kinetic studies, initiation is slow relative to propagation.
Joseph P. Kennedy   +2 more
openaire   +1 more source

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