Results 211 to 220 of about 19,599 (310)

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

NH3‐Guided Low‐Temperature Nanostructural Refinement Boosts Visible‐Light‐Driven H2O2 Synthesis in Ionic Carbon Nitrides

open access: yesAdvanced Materials, EarlyView.
A nanostructural refinement strategy is reported for KPHI photocatalysts using NH4Cl in a molten salt environment to induce coherent domain fragmentation and controlled cyano defect formation. This dual modification promotes n→π* transitions, enhances charge separation, and accelerates ORR kinetics, yielding exceptional AQY values of 49% (410 nm) and 5%
Jaya Bharti   +9 more
wiley   +1 more source

Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H2O2 Production via Data Science

open access: yesAdvanced Materials, EarlyView.
Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu   +3 more
wiley   +1 more source

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

open access: yesAdvanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez   +9 more
wiley   +1 more source

Reactive Carbide‐Based Synthesis and Microstructure of NASICON Sodium Metal All Solid‐State Electrolyte

open access: yesAdvanced Materials, EarlyView.
Sodium Metal All‐Solid State Batteries (Na‐ASSBs) are enabled by the synthesis of the solid state electrolyte, NASICON (Na1+xZr2SixP3‐xO12), using carbide‐based precursor compounds (ZrC and SiC); resulting in dense, pure, and mechanically improved microstructure.
Callum J. Campbell   +10 more
wiley   +1 more source

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