Results 141 to 150 of about 135,105 (302)

Tailoring Amine Substitution in Fluorene and Dibenzothiophene: A Molecular Strategy for Ultralong Organic Phosphorescence

open access: yesAdvanced Optical Materials, EarlyView.
Tailored amine substitution in fluorene and dibenzothiophene derivatives enables systematic control of excited‐state properties and triplet population. Combined photophysical studies, TD‐DFT calculations and time‐resolved EPR reveal how charge‐transfer character, sulfur‐induced spin–orbit coupling and triplet manifold engineering cooperate to promote ...
Francesco Ruighi   +10 more
wiley   +1 more source

Regioselective π‐Extension of Helical PAHs: Tuning Energy Gaps and Excited‐State Dynamics Directed by Clar's Sextet Migration

open access: yesAdvanced Optical Materials, EarlyView.
Central and terminal ring fusions of per‐peri‐perbenzo[7]helicene (PB[7]H) yield novel helical polycyclic aromatic hydrocarbons (HPAHs). The migration of Clar's aromatic sextets governs the inner‐rim stiffness. This topology‐directed strategy bridges the discrete optical gaps of homologous series. Transition moment density (TMD) analysis visualizes the
Zhibo Liu   +3 more
wiley   +1 more source

Revealing Mechanofluorochromism and Intricate Long‐lived Decay Pathways in Keto‐Coumarin‐Based Molecular Crystals

open access: yesAdvanced Optical Materials, EarlyView.
Donor–acceptor organic emissive materials show great promise in cutting‐edge optical applications. Herein, the photophysical properties of two keto‐coumarin organic materials are studied in detail. Both show mechanofluorochromism, but a diphenylamine donor derivative exhibits intricate decay pathways in the crystal form, including decays ranging from ...
Peter W. McDonald   +6 more
wiley   +1 more source

A Layered Two‐Dimensional Hydrogen‐Bonded Organic Framework Based on 2,5,8,11‐Tetrakis(4‐Carboxyphenyl)Perylene Diimide: Structural Nature, Optical and Photophysical Properties

open access: yesAdvanced Optical Materials, EarlyView.
A novel hydrogen‐bonded organic framework (HOF) based on perylene diimide (PDI) is synthesized, structurally and spectroscopically characterized. Its photophysical behavior highlights how supramolecular organizations govern the optical properties, including emission from monomers, aggregates, and excimer‐like species. Structural transformations induced
Mario de la Hoz Tomás   +9 more
wiley   +1 more source

Nanomaterial‐Incorporated Nonlinear Optical Waveguides Explored With All‐Fiber Multiphoton Polymerization

open access: yesAdvanced Optical Materials, EarlyView.
Nonlinear waveguides are fabricated via an all‐fiber‐based multiphoton polymerization approach incorporating upconversion nanoparticles (UCNPs), which enable both multiphoton absorption at telecommunication wavelengths and nonlinear saturable absorption operation.
Bowon Ryu   +7 more
wiley   +1 more source

Home - About - Disclaimer - Privacy