Results 251 to 260 of about 808,060 (334)

Long-lived multilevel coherences and spin-1 dynamics encoded in the rotational states of ultracold molecules. [PDF]

open access: yesNat Commun
Hepworth TR   +5 more
europepmc   +1 more source

Aromaticity‐Switchable Tetraoxa[8]circulenes as Anode Materials for Sodium‐Ion Batteries

open access: yesChemistryEurope, EarlyView.
Aromaticity‐based electrode materials have received substantial interest in recent years. Herein, a naphtho‐tetraoxa[8]circulene (N‐TOC) is introduced, its electrochemical performance is investigated, and its charge‐storage mechanism through aromaticity switching described by computational calculations.
Patrick W. Fritz   +7 more
wiley   +1 more source

Abrupt structural transition in exotic molybdenum isotopes unveils an isospin-symmetric island of inversion. [PDF]

open access: yesNat Commun
Ha J   +31 more
europepmc   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Photoinduced Electron Transfer (PET) as Key to Accelerate the Cycloreversion Reaction of Arylquadricyclanes

open access: yesChemistry – A European Journal, EarlyView.
It is demonstrated that the photoinduced cycloreversion of a methoxynaphthylquadricyclane in the presence of suitable photocatalysts gives quantitatively the corresponding norbornadiene. As this photochromic norbornadiene‐quadricyclane cycle has favorable properties for light energy conversion, this method provides a useful tool for the targeted ...
Julian Felix Maria Hebborn   +4 more
wiley   +1 more source

Simultaneous Grafting of 3,4,5‐Trihydroxypiperidine Iminosugars Onto Multivalent Scaffolds via Double Reductive Amination Provides New GCase Inhibitors

open access: yesChemistry – A European Journal, EarlyView.
A small set of low‐valency multivalent 3,4,5‐trihydroxypiperidines was prepared through double reductive amination (DRA) of a sugar‐derived dialdehyde. Among them, trivalent derivative 37 emerged as a potent β‐glucocerebrosidase (GCase) inhibitor displaying an unexpected mixed‐type kinetic profile. The integration of kinetic analysis, NMR, docking, and
Maria Giulia Davighi   +10 more
wiley   +1 more source

Artificial intelligence as a ploy to delve into the intricate link between genetics and mitochondria in patients with MASLD. [PDF]

open access: yesJHEP Rep
Longo M   +17 more
europepmc   +1 more source

A Riboflavin‐Derived Flavinium Salt Mediates Chemoselective Methylation Reactions

open access: yesChemistry – A European Journal, EarlyView.
A two‐component methylation protocol was developed, where the active flavin mediator can be recycled in a single step. Crystallographic data and NMR spectroscopy support the mechanistic proposal, while chemoselective methylation was observed for a broad range of biologically relevant substrates. ABSTRACT Selective methylation is among the most relevant
Tim Langschwager   +3 more
wiley   +1 more source

Newly-engineered angiopoietin-1 as a cell-priming agent for CVD. [PDF]

open access: yesCell Mol Life Sci
Kang J   +7 more
europepmc   +1 more source

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