Results 171 to 180 of about 22,267 (217)

Sonochemical Synthesis of Cobalt‐Oxo‐Cubanes as Redox‐Active Platform for Proton‐Coupled Electron Transfer

open access: yesChemistry – A European Journal, EarlyView.
A facile sonochemical method for rapid and gram‐scale synthesis of ligand‐tunable cobalt‐oxo‐cubanes is reported. Electrochemical studies reveal a Co4O4‐centered one‐electron oxidation and PCET pathway, while identifying Co2+ impurities as key disruptors of true cubane redox chemistry.
Satyapriya Nath   +8 more
wiley   +1 more source

Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide

open access: yesChemistry – A European Journal, EarlyView.
Common main group reductants selectively convert nitrogen dioxide to nitric oxide in a catalyst‐free manner. Computational studies suggest divergent reaction pathways depending on the reductant employed. Where boranes and silanes proceed via a two‐electron process, and hydrogen surrogates undergo stepwise one‐electron processes.
Awais W. Seyyad   +3 more
wiley   +1 more source

Influence of Head‐to‐Tail Cyclization of Lanmodulin‐Inspired Peptides on Lanthanide Affinity and Structure

open access: yesChemistry – A European Journal, EarlyView.
The influence of head‐to‐tail cyclization, as well as the effect of ring expansion with an additional glycine on lanmodulin‐inspired peptides on the structure and lanthanide (Ln)‐binding behavior was investigated. While the decrease of structural flexibility can indeed increase the Ln affinity and peptide pre‐organization, it does not lead to an ...
Sophie M. Gutenthaler‐Tietze   +6 more
wiley   +1 more source

Peroxodisulfate‐Enhanced Leaching of Deep‐Sea Manganese Crusts and Sulfides

open access: yesChemie Ingenieur Technik, EarlyView.
Ammonium peroxodisulfate enables efficient leaching of deep‐sea manganese crusts and massive sulfides while offering electrolytic recycling. High leaching yields for V, Mn, Co, Mo, Sn, and W, along with complete leaching of As and Sb, highlight its potential as a powerful and sustainable oxidant for marine resource processing.
Bastian Hansel   +5 more
wiley   +1 more source

Green and sustainable synthesis of magnetite from copper slag via citrate complexation for methylene blue dye removal from water

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study proposes a novel, green, and sustainable method for synthesizing magnetic iron oxides from metallurgical copper slag (CS), leveraging its iron content as a valuable resource. Iron was extracted via acid leaching using edible citric acid (ECA), forming a citrate–iron complex (CSL), which was subsequently thermally decomposed at 300°C
Melisa Portilla‐Sangabriel   +4 more
wiley   +1 more source

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