Results 131 to 140 of about 34,201 (289)

Remote Roca: Integrating Data From Archaeological Survey, Remote Sensing and Geophysics in the Hinterland at the Long‐Lasting Mediterranean Site of Rocavecchia (Apulia, Italy)

Archaeological Prospection, EarlyView.
ABSTRACT This study presents a multi‐method non‐invasive investigation of an approximately 4‐ha area associated with the long‐occupied coastal settlement of Rocavecchia (Apulia, southern Italy), situated between the prehistoric fortified peninsula and the Hellenistic‐Messapian walls.
Giuseppe Guarino, Francesco Iacono, Giovanna Agostini, Davide Susini   +3 more
wiley   +1 more source

Poseidon's Sanctuary at Samikon—The Discovery of an Ancient Temple Through an Integrated Geophysical and Geoarchaeological Survey Approach for Lagoonal and Swampy Environments

Archaeological Prospection, EarlyView.
ABSTRACT Below the classical fortress of Samikon at the coast of the western Peloponnese, ancient writer Strabo mentioned a sanctuary of Poseidon which served as the centre of the religious association of the Triphylian cities. In this paper, we describe the discovery and investigation of a building structure by means of geophysical and ...
Dennis Wilken, Birgitta Eder, Sarah Bäumler, Elena Appel, Peter Fischer, Tina Georg, Federica Iannone, Lena Slabon, Timo Willershäuser, Erofili‐Iris Kolia, Andreas Vött   +10 more
wiley   +1 more source

Electronic Resonance Network Stabilized Crystal Structure in High‐Nickel Cathodes for Lithium‐Ion Batteries

Carbon Energy, EarlyView.
Transition metal (TM) ions with empty eg orbitals induce single‐electron delocalization in Ni3+ to form the resonance structure of Ni─OO─TM through the high‐entropy effect. High‐nickel cathode materials with electron resonance structure have the advantages of improving thermodynamic stability, suppressing phase transitions, and mitigating lattice ...
Yi Li, Qinwen Cui, Jinpeng Li, Xingyu Li, Liang Yin, Erhong Song, Youwei Wang, Xiaolin Zhao, Jianjun Liu   +8 more
wiley   +1 more source

T½ Tuning in a Synergistic BODIPY‐Tetrazole Fe(II) Spin‐Crossover‐Photoluminescence System via Co‐Ligand Variation

Chemistry – A European Journal, EarlyView.
We report a modular spin crossover‐photoluminescence (SCO‐PL) system: heteroleptic, mononuclear Fe(II) coordination compounds bearing equatorial BODIPY fluorophores that exhibit synergistic PL response upon spin state switching. Exchanging apical nitrile co‐ligands tunes electronic and structural properties, giving precise control over the SCO and PL ...
Martin Huber, Matthias Schöbinger, Berthold Stöger, Michael Reissner, Peter Weinberger   +4 more
wiley   +1 more source

Influence of Carboxylate Ligand Variation on Structure, Magnetic Exchange, and Magnetocaloric Performance in Hexanuclear Gd(III) Complexes

Chemistry – A European Journal, EarlyView.
ABSTRACT Hexanuclear cyclic Gd(III) coordination compounds are promising candidates for magnetic and magnetocaloric applications, yet systematic series remain rare due to synthetic challenges. We report the synthesis and characterization of five new complexes with the general formula [Gd(H3bt)(carboxylate)]6, employing four different carboxylate ...
Ondřej František Fellner, Kamil Kotrle, Erik Čižmár, Jana Brázdová, Pavel Štarha, Ján Moncoľ, Radovan Herchel, Ivan Nemec   +7 more
wiley   +1 more source

Ladder‐Like Structural Architecture of Layered Magnetic A2.4 Cr8Te14 (A = Rb, Cs) Compounds by Self‐Flux Synthesis

Chemistry – A European Journal, EarlyView.
A2.4Cr8Te14$A_{2.4}{\rm Cr}_{8}{\rm Te}_{14}$ (A = Rb, Cs) compounds exhibit a layered, ladder‐like Cr‐Te framework uniting structural motives of hollandite‐like and delafossite‐like phases. Alkali atoms are situated both in the interlayer space and tunnels within the Cr8Te14${\rm Cr}_{8}{\rm Te}_{14}$ framework.
Kai D. Röseler, Felix Eder, Fabian O. von Rohr   +2 more
wiley   +1 more source

A High Energy Barrier DyIII2 Single‐Molecule Magnet Supported by a Bulky, Anionic N–O Bridging Ligand

Chemistry – A European Journal, EarlyView.
Complex [Dy2(hynad)2(dbm)4] was prepared by the employment of the anionic N–O‐based bridging and chelating N‐hydroxy‐1,8‐naphthalimide ligand, featuring a {Dy2(µ‐OR)2}4+ core and exhibiting zero‐field SMM behavior with a Ueff value of 171 K and double‐S‐shaped hysteresis loops, open up to 3.5 K.
Alexandros S. Armenis, Concepción Molina‐Jirón, Konstantinos N. Pantelis, Wolfgang Wernsdorfer, Mario Ruben, Eufemio Moreno‐Pineda, Theocharis C. Stamatatos   +6 more
wiley   +1 more source

A Novel Heterometallic Ring {Cr5Ni3} and New {Cr6Co2} and {Cr6Zn2} Rings

Chemistry – A European Journal, EarlyView.
A novel heterometallic ring containing five Cr(III) and three Ni(II) centers is reported. It forms an octagon and has a single isomer, as revealed by a combination of magnetic and EPR studies and collision‐induced dissociation mass spectrometry. ABSTRACT A new heterometallic ring, [Me4N][(Me4N)2Cr5Ni3F8(BTFB)16] (BTFB = 3,5‐bis(trifluoromethyl)benzoate)
Abdulelah Alsuhaymi, Niklas Geue, Adam Brookfield, Grigore A. Timco, Selena J. Lockyer, Gareth D. Smith, George F. S. Whitehead, Perdita E. Barran, David Collison, Richard E. P. Winpenny   +9 more
wiley   +1 more source

AI‐Driven Precision Annealing for High Performance Fe‐Based Amorphous Alloys

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The four stages of the research process are as follows: First, data is collected and a database is constructed. This is followed by feature selection and analysis, then the establishment of machine learning models, and finally formulation design and preparation.
Yichuan Tang, Shaopeng Liu, Silong Li, Ruonan Ma, Peinan Li, Zheng Wang, Kun Wang, Kaiyan Cao, Sidan Ding, Chao Zhou, Fanghua Tian, Sen Yang, Minxia Fang, Yin Zhang   +13 more
wiley   +1 more source

Nanofiber PVA‐Based Membranes Incorporating Functionalized Spanish Broom Derivatives for Sustainable Water Purification

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study investigates Spanish broom (Spartium junceum) as a renewable source for electrospun composite membranes in sustainable water purification. MCC and biochar were functionalized with eco‐friendly precursors and nanomaterials (i.e., HNT, β‐CDs) to develop hybrid PVA nanofiber composites.
Giulia Rando, Silvia Sfameni, Jozefien Geltmeyer, Alessandra Palella, Lorenzo Spadaro, Alberto Riminucci, Karen De Clerck, Maria Rosaria Plutino   +7 more
wiley   +1 more source