A Mechanical sp2‐Jail for C60 Fullerene
A rigid bisporphyrin receptor with an exceptionally compact 3D cavity functions as a molecular “mechanical jail”, tightly enclosing C60 fullerene. Near‐perfect shape complementarity affords ultrahigh binding affinity while imposing a large kinetic barrier for guest exchange, rendering encapsulation effectively irreversible under ambient conditions ...
A. Priscila Gia +8 more
wiley +2 more sources
Up-to-date MALDI-TOF MS-based identification of the <i>Corynebacterium diphtheriae</i> species complex for improved diagnostics. [PDF]
Rau J +10 more
europepmc +1 more source
Methionine Regulates Antitumour Function of CD8+ T Cells Through Polyamine Synthesis
Methionine restriction in vitro enhances CD8+ T cell effector function by suppressing polyamine synthesis and progressively induces the co‐expression of PD‐1 and TIM‐3. Consistently, sustained dietary methionine restriction diminishes the efficacy of adoptive T cell therapy (ACT) and promotes the expression of terminal exhaustion‐associated markers ...
Tian Zhao +16 more
wiley +1 more source
Substrate‐Dependent Crosslinking by the Cytochrome P450 From Aminopyruvatide Biosynthesis
Substitutions in the aminopyruvatide precursor peptide altered the C─C linkage formed from a YLY motif by the P450 ApyO to a N─C linkage in a WLY motif. Moreover, constitutional isomers crosslinked by C─C and C─O linkages were formed from YYY or YWY motifs. ABSTRACT Cytochrome P450s catalyze an array of reactions including crosslinking of aromatic side
Chandrashekhar Padhi +6 more
wiley +2 more sources
Impact of rapid MALDI-TOF MS and susceptibilities on hospitalized children with Gram-negative bloodstream infections. [PDF]
Santos ME +6 more
europepmc +1 more source
ABSTRACT Vibrio harveyi is an important bacterial pathogen in marine aquaculture, responsible for outbreaks affecting a wide range of fish species. Early detection of potentially virulent isolates in fish and environmental samples is essential for effective disease prevention and management, particularly under field conditions where the pathogen may be
Javier Barriga‐Cuartero +4 more
wiley +1 more source
Self‐assembled tetrahedral CoI4 clusters supported by simple bipyridine‐based ligands undergo core rearrangement to cleave S─F and C(sp2)─F bond, forming fluoride‐bridged tetracobalt(II)‐oxo clusters, while exposure of cobalt(I) clusters to molecular oxygen yields cubane‐type cobalt(III) oxo clusters.
Hoan M. Dinh +4 more
wiley +2 more sources
Integrated MALDI-TOF MS, Microbiological, Physicochemical and Sensory Assessment of Spoilage in Vacuum-Packaged Chicken Breast During Refrigerated Storage. [PDF]
Söylemez Milli N.
europepmc +1 more source
ABSTRACT Background Black yeast‐like species of the order Chaetothyriales cause superficial to life‐threatening systemic infections. Comprehensive global epidemiology data remain limited. Objectives This study aimed to analyze the global epidemiology, spectrum of pathogens, clinical manifestations and outcomes of Chaetothyriales infections.
Jiayi Li +6 more
wiley +1 more source
Development and validation of the first species-specific MALDI-TOF MS main spectra profile database for rapid identification of Aeromonas schubertii associated with white nodular disease in freshwater fish. [PDF]
Mursalim MF +5 more
europepmc +1 more source

