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Characterizing and compensating for matrix effects using atmospheric pressure chemical ionization liquid chromatography-tandem mass spectrometry: analysis of neutral pharmaceuticals in municipal wastewater.

Analytical Chemistry, 2008
Matrix effects are a great challenge for the quantitative analysis of environmental samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Signal suppression or enhancement can compromise the accuracy of analytical results.
Xiaoming Zhao, C. Metcalfe
semanticscholar   +1 more source

Chemical analysis and distribution investigation of trace elements in indium matrix by spark source mass spectrometry

Fresenius' Zeitschrift für analytische Chemie, 1987
High-purity indium was analysed by spark source mass spectrometry, using electrical and photoplate detection. For the calibration of the differences in elemental sensitivity, a standard sample was prepared in which 10 impurities were determined by graphite furnace atomic absorption spectrometry. In this way accuracies of less than 40% were obtained for
X. D. Liu, F. C. Adams, P. Van Espen
openaire   +2 more sources

Direct Analysis of Volatile Methylsiloxanes in Gaseous Matrixes Using Atmospheric Pressure Chemical Ionization-Tandem Mass Spectrometry

open access: closedAnalytical Chemistry, 2009
Atmospheric pressure chemical ionization-tandem mass spectrometry (APCI-MS/MS) was applied for the first time to the direct analysis of octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5) in gaseous matrixes without extraction or prior chromatographic separation.
Koffi Badjagbo   +4 more
openalex   +4 more sources

Matrix effects during analysis of plasma samples by electrospray and atmospheric pressure chemical ionization mass spectrometry: practical approaches to their elimination.

Rapid Communications in Mass Spectrometry, 2003
Some cases of occurrence of matrix effects (mostly ion suppression) in protein-precipitated plasma samples, and their influence on the validity of plasma concentrations and pharmacokinetic parameters, are discussed. The comparison of matrix effects using
J. Schuhmacher   +3 more
semanticscholar   +1 more source

Generation of an Industry-specific Physico-chemical Allocation Matrix. Application in the Dairy Industry and Implications for Systems Analysis (9 pp)

The International Journal of Life Cycle Assessment, 2007
Allocation is required when quantifying environmental impacts of individual products from multi-product manufacturing plants. The International Organization for Standardization (ISO) recommends in ISO 14041 that allocation should reflect underlying physical relationships between inputs and outputs, or in the absence of such knowledge, allocation should
A. Feitz   +4 more
semanticscholar   +3 more sources

Recursive NARX model identification of nonlinear chemical processes with matrix invertibility analysis

Computers & Chemical Engineering, 2019
Abstract In the learning techniques based on kernel or orthogonal basis functions, the nonlinearity in the underlying complex dynamic process is modelled by a linear combination of a set of kernel or orthogonal basis functions. Once these functional parameters are selected, the learning task boils down to solving linear least squares (LS).
openaire   +2 more sources

Multichannel Mueller matrix analysis of the evolution of the microscopic roughness and texture during ZnO:Al chemical etching

Conference Record of the Thirty-first IEEE Photovoltaic Specialists Conference, 2005., 2005
Transparent conducting oxides (TCOs) are used in thin film silicon (Si:H) photovoltaics (PV) technology as top electrical contacts and as the components of back-reflecting structures. TCOs are often prepared with macroscopically rough interfaces and/or surfaces (i.e., with "texture") in order to scatter light and thereby enhance optical path lengths in
Nikolas J. Podraza   +4 more
openaire   +2 more sources

Quantification of the effects of secondary matrix on the analysis of sandstone composition, and a petrographic-chemical technique for retrieving original framework grain modes of altered sandstones.

Journal of sedimentary research. Section A, Sedimentary petrology and processes : an international journal of SEPM, 1996
Most studies of sandstone provenance involve modal analysis of framework grains using techniques that exclude the fine-grained breakdown products of labile mineral grains and rock fragments, usually termed secondary matrix or pseudomatrix.
R. Cox, D. Lowe
semanticscholar   +1 more source

A holistic approach combining factor analysis, positive matrix factorization, and chemical mass balance applied to receptor modeling

Environmental Monitoring and Assessment, 2013
Rapid urbanization and population growth resulted in severe deterioration of air quality in most of the major cities in India. Therefore, it is essential to ascertain the contribution of various sources of air pollution to enable us to determine effective control policies.
S. Pushpavanam, N. Selvaraju, N. Anu
openaire   +3 more sources

Integrative and Personalized QSAR Analysis in Cancer by Kernelized Bayesian Matrix Factorization

Journal of Chemical Information and Modeling, 2014
With data from recent large-scale drug sensitivity measurement campaigns, it is now possible to build and test models predicting responses for more than one hundred anticancer drugs against several hundreds of human cancer cell lines.
Muhammad Ammad-ud-din   +7 more
semanticscholar   +1 more source

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