The Preparatory (Anti)Bonding Character of Molecular Orbitals
Advanced Science, EarlyView.Herein, a concept to qualitatively predict changes in bond dissociation energies upon reduction or oxidation of molecular compounds is introduced. Changing the population of so‐called preparatory molecular orbitals influences how molecular fragments are relaxing after bond cleavage, which is shown for isolated organometallic aluminum compounds as well ...
Jonas O. Wenzel +10 more
wiley +1 more source
Intraosseous Schwannoma Arising within the Thoracic Vertebra: A Case Report. [PDF]
Case Rep OncolIwanaka M +8 more
europepmc +1 more source
Emergent Spinning and Orbital Motion in Clustered Wind‐Assisted Flyers
Advanced Science, EarlyView.Inspired by natural snowflake geometries, paper‐cut flyers exhibit geometry‐defined spinning and orbital motions during cluster formation in a wind tunnel. Collective flights of multiple paperflakes reveal dynamic clustering, fragmentation, and continuously evolving spin behaviors.
Bingnan Zhou +7 more
wiley +1 more source
Remote Orthotic Fabrication Method Using Small Three-Dimensional Printers and Computed Tomography Data: A Technical Report. [PDF]
Fukushima J Med SciYokota T +10 more
europepmc +1 more source
Advanced Science, EarlyView.This work presents a magnetic‐bearing acoustic resonator that overcomes the thermodynamics limit of sound absorption. By introducing tunable negative stiffness, it achieves broadband low‐frequency absorption within a compact cavity, far exceeding the performance achievable by classic mass‐tuned designs.
Ying Hu +5 more
wiley +1 more source
A Case of Lumbar Spondylodiscitis Caused by Klebsiella oxytoca in the Specimen Collected from Endoscopic Surgery. [PDF]
NMC Case Rep JDoi K +4 more
europepmc +1 more source
Advanced Science, EarlyView.scTIDE identifies single‐cell tipping points by combining manifold‐based graph representations with optimal‐transport conditional flow matching, which preserves intrinsic topology and models distributional dynamics. It supports critical‐transition detection at individual‐cell resolution, prediction of unseen cells, and dimensionality reduction and ...
Jiayuan Zhong +6 more
wiley +1 more source
Examining the effectiveness of ChatGPT responses to frequently asked questions by individuals with postural disorders. [PDF]
Rev Assoc Med Bras (1992)Dursun B, Torlak MS, Tufekci O.
europepmc +1 more source
Advanced Science, EarlyView.Polydopamine nanoparticles enable a precise, non‐genetic, and transcranial neuromodulation strategy via near‐infrared photothermal stimulation. By activating TRPV1 channels, this approach specifically enhances hippocampal gamma oscillations, thereby rescuing spatial memory deficits in models of perioperative neurocognitive disorder.
Yan‐Bo Zhou +10 more
wiley +1 more source
Fighting the Fracture Cascade: Early and Repeated Balloon Kyphoplasty as a Bridge Until the Effects of Osteoporosis Treatment Become Apparent in a Super-Aged Patient. [PDF]
CureusTanaka T +5 more
europepmc +1 more source