Results 131 to 140 of about 29,332 (208)

Two‐Step Synthesis of a Chiral Fluorinated Alcohol With Silica‐Supported Enzyme RrADH in Batch and Continuous Flow Mode

open access: yesChemistry – A European Journal, EarlyView.
A two‐step process was transferred from batch to flow mode for the synthesis of (R)‐2‐fluoro‐1‐phenylethanol as a benchmark, consisting of a decarboxylative fluorination in aqueous media, followed by an enantioselective biocatalytic reduction of the prochiral intermediate with RrADH immobilized on silica supraparticles.
Egzon Cermjani   +7 more
wiley   +1 more source

Photoelectrochemical Hydrogen Peroxide Production via Simultaneous Reduction and Oxidation Processes

open access: yesChemistry – A European Journal, EarlyView.
Hydrogen peroxide (H2O2) is an important chemical substance and also a promising carbon‐free clean fuel. The design of a sophisticated photoelectrochemical (PEC) reaction system enables the solar‐driven H2O2 production through simultaneous water oxidation and oxygen reduction processes (H2O2/H2O2‐PEC cells).
Tetsuro Soejima   +2 more
wiley   +1 more source

Boron Neutron Capture Therapy at a Crossroads: Translational Gap and Emerging Delivery Agents

open access: yesChemistry – A European Journal, EarlyView.
This review surveys recent advances in boron delivery agents for BNCT, emphasizing the shift from classical small molecules to multifunctional nanocarriers and theranostic systems. By integrating targeting, imaging, and therapy, next‐generation boron compounds aim to bridge the gap between (bio)chemical innovation and clinical translation.
Christoph Selg, Evamarie Hey‐Hawkins
wiley   +1 more source

It's a Gas: Bioconjugation With Vapor‐Phase Reagents

open access: yesChemistry – A European Journal, EarlyView.
Gaseous reagents are an emerging class of bioconjugation reagents that can offer alternative selectivity paradigms for the construction of precise bioconjugates. A variety of both inert and highly reactive gases have recently been developed for bioconjugation use.
Yuxuan Ding, Jun Ohata, Zachary T. Ball
wiley   +1 more source

In Situ Methanation on Mars: A Process Concept Study on the Impact of H2/CO2 and Recycle Ratio

open access: yesChemie Ingenieur Technik, EarlyView.
The rocket propellant methane can be produced on Mars by in situ resource utilization. The H2/CO2 ratio is decisive, and excess H2 is favored for providing sufficient propellant purity. The operation mode—with or without recycling of unreacted reactants—depends on the resource availability of the selected landing site. Abstract For return missions from
Franz Braun   +4 more
wiley   +1 more source

Integration of High‐p, Low‐T CO2 Electrolysis with Pressure Swing Adsorption Purification

open access: yesChemie Ingenieur Technik, EarlyView.
We evaluate a high‐p low‐T CO2 electrolysis (LTCE) cell with a pressure swing adsorption (PSA) to compare cascade vs. recycle operation. Although a cascade yields high CO selectivity but limited yield, a full recycle achieves near‐quantitative CO production, highlighting gas recycling as essential for LTCE/PSA systems.
Martin Peters   +5 more
wiley   +1 more source

Modelling of continuous low‐temperature emulsion co‐polymerization in 3D‐printed reactor

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
A kinetic model for the emulsion copolymerization of butyl acrylate/styrene at low temperatures is proposed and validated against experiments with a redox initiator system. The model was successfully transferred to a 3D‐printed tubular reactor and conversions of more than 80% and small particles sizes below 40 nm were observed.
Ferel Issa   +2 more
wiley   +1 more source

Sensitivity analysis and stochastic optimization of levelized cost of hydrogen production through methane pyrolysis

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Hydrogen plays a crucial role across multiple industrial sectors and is increasingly recognized as a clean energy carrier with significant potential in decarbonization efforts. Methane pyrolysis (MP), particularly using molten metal catalysts, offers a promising pathway for hydrogen production with low CO2 emissions.
Adrian Paredes Bozzo, Zukui Li
wiley   +1 more source

Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque   +3 more
wiley   +1 more source

Beyond hydrogen: Process design of a biogas steam reformer for Fischer–Tropsch synthesis

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
The effect of pressure and steam to carbon ratio on carbon conversion. Abstract We present an analysis of a pilot‐scale multi‐tubular biogas steam reforming reactor, part of a sustainable aviation fuel (SAF) development project in Brazil. The novelty of this work is the application of a new, validated power law kinetic model, specifically developed for
Rafael Belo Duarte   +3 more
wiley   +1 more source

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