Results 61 to 70 of about 1,452,341 (273)

Design and optimization of a catalytic membrane reactor for the direct synthesis of propylene oxide

open access: yes, 2015
Using numerical simulations, a new membrane reactor is proposed for the direct synthesis of propylene oxide (PO) in liquid phase. The reactor is a combination of two consecutive catalytic reactor units, one for the hydrogen peroxide (H2O2) synthesis on a
Neira d'Angelo, M.F.   +3 more
core   +1 more source

Defect‐Engineered Microwave‐Responsive Ni@C Composites From Waste PET for Catalytic Plastic Upcycling

open access: yesAdvanced Materials, EarlyView.
A circular upcycling strategy transforms waste poly(ethylene terephthalate) bottles into microwave‐responsive Ni@C catalyst featuring lattice‐distorted nickel cores and defective carbon shells. These strain‐rich heterointerfaces enhance dielectric loss and promote localized microwave hotspots, accelerating peroxymonosulfate activation and polymer‐chain
Xiao Lu   +7 more
wiley   +1 more source

Beyond Nanoporosity: A CO2‐Conditioned Glassy Matrix Contributes to the Brittle‐to‐Ductile Transition of Nanocellular Polyetherimide

open access: yesAdvanced Materials, EarlyView.
The mechanical performance of nanocellular polyetherimide cannot be explained by nanoporosity alone. It is shown that CO2 saturation and desorption leave a distinct mechanical signature in the glassy matrix before foaming. This matrix contribution provides a new route to understand and optimize the brittle to ductile transition in nanocellular polymers.
Félix Lizalde‐Arroyo   +7 more
wiley   +1 more source

Optimizing membrane reactor structures for enhanced hydrogen yield in CH4 tri-reforming: Insights from sensitivity analysis and machine learning approaches

open access: yesInternational Journal of Thermofluids
This study explores the optimization of membrane reactor configurations to enhance hydrogen production through CH4 tri-reforming. The investigation employs ceramic membranes for oxygen, vapor, and carbon dioxide distribution within the reactor bed.
Mohammadali Nasrabadi   +4 more
doaj   +1 more source

Hierarchical Flexible Ceramic Nanofiber Membrane for Simultaneous Membrane Distillation and Photocatalytic Hydrogen Evolution

open access: yesAdvanced Materials, EarlyView.
A hierarchical flexible ceramic nanofiber membrane integrates a La‐stabilized ZrO2 scaffold with superhydrophobic UiO‐66‐NH2/CdS heterojunctions. The gas–liquid–solid interfacial architecture sustains vapor‐selective desalination, visible‐light charge separation, and rapid H2 extraction, enabling simultaneous freshwater production and photocatalytic ...
Pengfei Lin   +9 more
wiley   +1 more source

Redox‐Confined Interfacial Polymerization Enables Mechanically Robust and Self‐Adhesive Nanofilms

open access: yesAdvanced Materials Interfaces, EarlyView.
Redox‐confined polymerization of a simple thiol monomer at a water‐organic interface generates robust freestanding films with nanoscale thickness. The resulting disulfide‐crosslinked nanofilms combine high stiffness with intrinsic adhesion to soft substrates, enabling conformal contact with artificial skin without additional functionalization.
Luana Gazzato   +4 more
wiley   +1 more source

UCST‐Responsive PMEGA: From Solution Behavior to Functional Hydrogel Surfaces

open access: yesAdvanced Materials Interfaces, EarlyView.
PMEGA is used as a versatile water‐based UCST‐responsive platform for engineering microstructured hydrogel coatings via a thiol–ene CLAG approach. From PMEGAs of well‐defined UCST properties, the UV‐based CLAG method provides precise control over film thickness, ranging from nanometers to micrometers, and enables high‐resolution patterning.
Thi Phuong Thu Nguyen   +4 more
wiley   +1 more source

Electrochemically-driven solid oxide tubular membrane reactor for efficient separation of oxygen and argon

open access: yesJournal of Membrane Science Letters
The high purity of Ar is crucial for industrial applications such as steel production, welding, and laboratory use, while the similar physical properties of O2 and Ar make their efficient separation challenging.
Yuanhui Tang   +6 more
doaj   +1 more source

Advanced MXene‐Based Multifunctional Nanoarchitecture Materials Engineered for Adsorptive Cleanup of Hazardous Radioactive Pollutants: A Comprehensive Critical Review

open access: yesAdvanced Materials Interfaces, EarlyView.
This work critically reviews MXenes as highly effective multifunctional nanomaterials for the adsorption of radio‐contaminants, demonstrating a remarkable adsorption capacity of up to 1376.75 mg/g and cyclic stability of 2–8 cycles, with complexation, electrostatic interactions, and the numerical strength of MXene active sites playing a key operational
Stephen Sunday Emmanuel   +1 more
wiley   +1 more source

Membrane Reactor Based on Hybrid Nanomaterials for Process Intensification of Catalytic Hydrogenation Reaction: an Example of Reduction of the Environmental Footprint of Chemical Synthesis from a Batch to a Continuous Flow Chemistry Process

open access: yesChemical Engineering Transactions, 2016
Membrane processes represent a well matured technology for water treatment with low environmental footprints compared to other type of processes. We have now combined this technology with nanomaterials, ionic liquids (negligible vapor pressure), and poly(
Y. Gu   +5 more
doaj   +1 more source

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