Results 111 to 120 of about 265,557 (264)
Advanced Materials, EarlyView.A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang +8 more
wiley +1 more source
Thermodynamics of Metal Complex Formation in Aqueous Solution. VIII. A Calorimetric Study of the Mercury(II) Thiocyanate, Selenocyanate, and Thiosulfate Systems. [PDF]
, 1974 Lennart Kullberg +5 more
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Spectral Tuning of Hyperbolic Shear Polaritons in Monoclinic Gallium Oxide via Isotopic Substitution
Advanced Materials, EarlyView.Spectral tuning of highly directional hyperbolic shear polaritons is realized via isotopic substitution of 16O to 18O in monoclinic β$\beta$‐phase gallium oxide. A red‐shift of almost 40 cm−1 is experimentally demonstrated with near‐field imaging, corroborated by the permittivity change extracted from far‐field experiments and density functional theory.
Giulia Carini +28 more
wiley +1 more source
Rapidly Dropping Mercury E lectrode in Alternating Current Polarography.
, 1958 Nobuyuki Tanaka, Mutsuo Kodama
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Porous Iridium Oxide Inverse Opal Catalysts Enable Efficient PEM Water Electrolysis
Advanced Materials, EarlyView.Porous iridium‐based inverse opal (IrOx‐IO) structures are introduced as high‐performance, unsupported PEM‐WE anode catalysts. Their electrochemical behavior is analyzed through porosity/surface area tuning, voltage breakdown, and circuit modeling.
Sebastian Möhle +4 more
wiley +1 more source
High‐Performance Zero‐Gap Glycerol‐Fed Electrolyzer for C3 Chemicals and Hydrogen Production
Advanced Materials, EarlyView.This work presents a dynamic, self‐regulating operation strategy that enables selective glycerol electrooxidation in the OER‐free regime, co‐producing C3 chemicals and hydrogen at cell voltages below 1.25 V. Voltage‐ and temperature‐resolved analyses define optimal operating conditions, achieving a sustained current density of 500 mA cm−2 at ∼1.21 V ...
Shayan Angizi +11 more
wiley +1 more source
Improving Ionic Conformality Across Polymer Electrolyte|Electrode Interfaces
Advanced Materials, EarlyView.Polymer electrolytes typically form physically intimate electrode interfaces but often fail to maintain continuous ionic pathways, critically limiting battery performance. Through strategic compositional design, this study introduces a molecular ionic composite electrolyte that effectively reduces interfacial ionic depletion, ensuring consistent ion ...
Jungki Min +12 more
wiley +1 more source
Advanced Materials, EarlyView.A systematic study of a series of porous organic cages with perfluorinated alkyl side‐chains of different lengths is presented. The structure‐property relationship of the various cages on gas sorption of highly potent greenhouse gases, such as perfluorocarbons (PFCs), sulfur hexafluoride (SF6), and nitrogen trifluoride (NF3) is investigated.
Ke Tian +8 more
wiley +1 more source