Results 81 to 90 of about 3,134 (251)

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

open access: yesChemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz   +6 more
wiley   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

open access: yesEcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Structure and Properties of Liquid Fe‐C Alloys at High Pressures by Experiments and First‐Principles Calculations

open access: yesGeophysical Monograph Series, Page 37-45., 2020

This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.

Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions

Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Bin Chen, Jianwei Wang
wiley  

+2 more sources

Advances in Design Strategy and Mechanism Insights for Alkaline Hydrogen Evolution Reaction: Multilevel Site Engineering and Structure–Activity Relationship

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review is about material design based on engineering multilevel sites from theoretical calculation and synthetic routes to mechanism, structure–activity relationship, challenges and perspectives for boosting hydrogen production in alkaline electrolyte. Electrolytic water splitting is a clean, carbon‐free method for producing green hydrogen and has
Ke Zhang   +9 more
wiley   +1 more source

Mercury (Hg) Isotope Biogeochemistry

open access: yesJournal of Environmental Chemistry, 2009
Mercury (Hg) is a globally distributed and highly toxic pollutant in the environment. Its mobility and biomagnification in aquatic food chains depend on its biogeochemistry and redox cycling. Hg isotope analysis is an important new tool for identifying Hg source and tracking Hg transformations in the environment.
TAKEUCHI, Akinori   +2 more
openaire   +2 more sources

Origin of Physicochemical and Mechanical Stability of Low‐Temperature Prepared TiO2‐Based Photocatalytic Films: Surface Hydroxyl Density Matching

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Material science advances show how surface chemistry improves low‐temperature prepared TiO2‐SiO2 composite films. Using a colloidal‐based synthesis method instead of a powdered‐based one, researchers exploit hydroxyl groups' interfacial interactions to create nanoscale structures with superior physicochemical and mechanical stability.
Andraž Šuligoj   +7 more
wiley   +1 more source

Mercury Isotopes as Biogeochemical and Ecological Tracers: Assessing Mercury Sources and Exposure Pathways in Food Webs. [PDF]

open access: yes
Monomethylmercury (MMHg) is a toxic and bioaccumulative compound that poses serious health threats to wildlife and humans consuming fish. There are significant uncertainties concerning the MMHg sources and exposure pathways to aquatic food webs and ...
Kwon, Sae Yun
core  

Geochemical and Geological Investigation of Skarn‐Type Pb–Zn Mineralization in Hastanetepe (Balya‐Balıkesir, Türkiye): An Approach Based on Fluid Inclusions, Sulphur Isotopes and Geochemical Data

open access: yesGeological Journal, EarlyView.
Integrated petrographic, mineralogical and geochemical data from the Hastanetepe Pb–Zn deposit (Balya, Türkiye) reveal multi‐stage hydrothermal alteration and a magmatic sulphur source. Fluid inclusion and sulphur isotope results indicate a complex fluid evolution responsible for skarn‐type Pb–Zn mineralization along limestone–dacite contacts ...
Esra Ünal‐Çakır
wiley   +1 more source

Nuclear Structure from Radioactive Decay. Annual Progress Report [PDF]

open access: yes, 1991
This report discusses nuclear structure from radioactive decay of the following: Neutron-Deficient Iridium Isotopes; Neutron-Deficient Platinum Isotopes; Neutron-Deficient Gold Isotopes; Neutron-Deficient Mercury Isotopes; Neutron-Deficient Thallium ...
Wood, J. L.
core   +1 more source

From Mn(II)3 to Mn(IV)3: Controlled Multielectron Oxidation and Hydrocarbon Oxygenation Within a 7‐Dipy Trinuclear Scaffold

open access: yesJournal of the Chinese Chemical Society, EarlyView.
A trinuclear manganese complex supported by the 7‐Dipy scaffold undergoes controlled multielectron oxidation from Mn(II)3 to high‐valent Mn(IV)3 states. Spectroscopic signatures, including 16‐line and geff ≈ 5 EPR features, reveal stepwise redox accumulation. The oxidized Mn3 cluster mediates efficient oxygen‐atom transfer to strong CH bonds, enabling
Yu‐Hsuan Chen, Peter Ping‐Yu Chen
wiley   +1 more source

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