Photophysics and Inverted Solvatochromism of 7,7,8,8-Tetracyanoquinodimethane (TCNQ) [PDF]
We report the absorption, fluorescence, and Raman spectroscopy of 7,7,8,8- tetracyanoquinodimethane (TCNQ) in a variety of solvents. The fluorescence quantum yields (QYs) of linear alkane solutions are similar to one another, but QY is shown to acutely ...
IIMORI Toshifumi +4 more
core +2 more sources
Spectroscopic Determination of Binding Constants of Modified β-cyclodextrins with Brooker’s Merocyanine [PDF]
Host-guest complexation occurs when a guest molecule is held inside a host molecule through weak molecular forces. β-cyclodextrin, a host molecule, has a variety of uses and is often applied in pharmaceuticals.
Hanson, Carly
core +2 more sources
Interfacial Force‐Focusing Effect in Mechanophore‐Linked Nanocomposites
Enhanced force transmission to mechanophores is demonstrated in polymer nanocomposite materials. Spiropyran (SP) mechanophores that change color and fluorescence under mechanical stimuli are functionalized at the interface between SiO2 nanoparticles and ...
Tae Ann Kim +4 more
doaj +1 more source
Acidochromic spiropyran–merocyanine stabilisation in the solid state
In this work, we present an innovative approach to stabilise the open-ring merocyanine form of a spiropyran compound. In the solid state, the merocyanine form is rarely observed, highlighting the importance of this contribution. Our concept is based on a
V. Seiler +6 more
semanticscholar +1 more source
Fluorescence Ratiometric Properties Induced by Nanoparticle Plasmonics and Nanoscale Dye Dynamics
Nanoscale transport of merocyanine 540 within/near the plasmon field of gold nanoparticles was recognized as an effective inducer of single-excitation dual-emission ratiometric properties.
Aron Hakonen
doaj +1 more source
Investigating nano-structured domains within ionic liquids: the effect of cation change on thermal equilibrium and relaxation of spiropyran and spirooxazine. [PDF]
The established belief that ionic liquids (ILs) behave as homogenous solvents such as that observed in molecular solvents has been challenged.1, 2 Previous use of solvatochromic probe dyes has allowed for the traditional parameter of ‘polarity’ to be ...
Byrne, Robert +2 more
core
Molecular Implementation of Sequential and Reversible Logic Through Photochromic Energy Transfer Switching [PDF]
Photochromic spiropyrans modified with fluorophores were investigated as molecular platforms for the achievement of fluorescence switching through modulation of energy transfer.
Andréasson, Joakim +5 more
core +1 more source
Photoactivation of an Acid-Sensitive Ion Channel Associated with Vision and Pain [PDF]
We describe the reversible photoactivation of the acid sensitive ligand-gated ion channel ASIC2a, a mammalian channel found throughout the central and peripheral nervous systems that is associated with vision and pain. We also show the activation of GLIC,
Dougherty, Dennis +3 more
core +2 more sources
Molecular First Hyperpolarizabilities of a New Class of Asymmetric Squaraine Dyes [PDF]
The molecular first hyperpolarizabilities (β) of a series of asymmetric squaraine dyes have been measured by electric-field-induced second harmonic generation; the dyes have negative β-values whose magnitudes are comparable to 4-N,N-dimethylamino-4 ...
Chen, Chin-Ti +2 more
core +1 more source
Studies on metal-ion complex formation of crown ether derivatives incorporating a photoionizable spirobenzopyran moiety by electrospray ionization mass spectrometry [PDF]
Metal-ion complexation of crown ether derivatives incorporating one and two spirobenzopyran units was investigated by electrospray ionization mass spectrometry.The crowned spirobenzopyran derivatives exhibited very different metal ion-complexing behavior
Arakawa Ryuichi +9 more
core +2 more sources

