Porous Metal–Organic Framework Nanoparticles [PDF]
Nanomaterials, 2022 Metal–organic frameworks (MOFs) are hybrid crystalline particles composed of metal cations and organic linkers. Ranging from micro- to nanoscale depending on the preparation conditions, they have achieved a prevalent position among porous materials.
Antonio Vargas-Berenguel +3 more
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Cu-BTC Metal−Organic Framework Modified Membranes for Landfill Leachate Treatment [PDF]
Water, 2019 In this study, Cu-BTC (copper(II) benzene-1,3,5-tricarboxylate) metal-organic frameworks (MOFs) were incorporated into the structure of polysulfone (PSf) ultrafiltration (UF) membranes to improve the membrane performance for landfill leachate treatment, whereby different concentrations of Cu-BTC (0.5, 1, 1.5, 2 wt%) were added to the PSf casting ...
Mahfar Mazani +3 more
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Rings and threads as linkers in metal–organic frameworks and poly-rotaxanes [PDF]
Chemical Communications, 2013 Coordination polymers and metal-organic rotaxane frameworks are reported where the organic linker is replaced by functionalised inorganic clusters that act as bridging ligands.
Whitehead, George F S +11 more
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Metal–Organic Framework-Based Catalysts: Chemical Fixation of CO2 with Epoxides Leading to Cyclic Organic Carbonates [PDF]
Frontiers in Energy Research, 2015 As a C1 feedstock, CO2 has the potential to be uniquely highly economical in both a chemical and a financial sense. In particular, the highly atom-economical acid-catalyzed cycloaddition of CO2 to epoxides to yield cyclic organic carbonates (OCs), a functionality having many important industrial applications, is an attractive reaction for the ...
M. Hassan eBeyzavi +6 more
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Integration of noble metal nanocrystals in a hollow metal organic framework shell
, 2023 Metal Organic frameworks (MOFs) encapsulating noble metal nanocrystals (NCs) have aroused great attention in catalysis, especially for selective catalysis owing to the existence of strong interfacial interactions and synergistic functions. In noble metal
Nicola, Pinna, Wei, Zhang
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Guest-responsive thermal expansion in the Zr-porphyrin metal-organic framework PCN-222
, 2022 We use powder X-ray diffraction under variable temperature to study the thermal expansion of the metal- organic framework PCN-222 with varying amounts of guest content.
Maxwell W., Terban +4 more
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De-solvation of metal complexes to construct metal-organic framework glasses
, 2023 Structural fine-tuning is an important challenge in the chemistry of metal-organic framework (MOF) glasses. Current approaches of thermally/mechanically-induced vitrification are limited for azolate/cyanide-based crystalline MOFs, while other MOF ...
Yong-Sheng, Wei +3 more
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Metal–Organic Framework‐Based Nanomaterials for Electrocatalytic Oxygen Evolution
, 2022 Oxygen evolution reaction (OER) is an energy-determined half-reaction for water splitting and many other energy conversion processes, such as rechargeable metal–air batteries and CO2 reduction, due to its four-electron sluggish process.
Liu, Y +7 more
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Machine learning prediction of open metal sites in metal-organic framework catalysts
, 2022 Metal-organic frameworks (MOF) have garnered much attention as promising catalysts due to their tunable porosity, high surface area, and diversity of catalytic metal clusters and organic linkers as building blocks.
Huixuan, Guo +4 more
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Advanced photocatalysts based on metal nanoparticle/metal-organic framework composites
, 2020 Photocatalysis, via conversion of light into valuable chemicals, is an economic and effective way to utilize inexhaustible solar energy for the sustainable development of our human society.
Zhu, Y, Guo, J, Wan, Y, Zhao, M, Tang, Z
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