Results 141 to 150 of about 169,966 (270)

Size-Dependent Spin Crossover and Bond Flexibility in Metal-Organic Framework Nanoparticles

Size reduction offers a synthetic route to tunable phase change behavior. Preparing materials as nanoparticles causes drastic modulations to critical temperatures (Tc), hysteresis widths, and the “sharpness” of first-order versus second-order phase ...
Carl, Brozek, Anastasia, Andreeva, Checkers, Marshall, Taichi, Nishiguchi, Satoshi, Horike, Kentaro, Kadota, Audrey, Davenport   +6 more
core   +1 more source

Solution‐Processed Two‐Dimensional Indium Oxide on Sodium‐Embedded Alumina for Reconfigurable Optoelectronic Synaptic Transistors

Advanced Functional Materials, EarlyView.
Wafer‐scale two‐dimensioanl In2Se3 oxidized into InOx on sodium‐embedded beta‐alumina enables multifunctional reconfigurable electronics. Sodium ions accumulate within distinct spatial distribution under drain‐controlle and gate‐controlled operation. Drain‐control operation gives controllability of ultraviolet‐driven optoelectronic synaptic conductance
Jinhong Min, Yonghyun Albert Kwon, Hyunbin Kim, Jihyun Kim, Myeongjin Jung, Jaewon Heo, Gwang Ya Kim, Vlastimil Mazanek, Zdeněk Sofer, In Soo Kim, Jeong Ho Cho, Hyesung Park, Sang Min Won, Joohoon Kang   +13 more
wiley   +1 more source

Direct synthesis of a semiconductive double-helical phosphorus allotrope in a metal-organic framework

Nature Communications
There remains much ambiguity regarding the structure of red phosphorus. We report the adsorption and photo-polymerisation of P4 molecules encapsulated in an indium(III)-based metal-organic framework to afford a double-helical chain composite comprising ...
Sergei A. Sapchenko, Rodion V. Belosludov, Inigo J. Vitoria-Irezabal, Ivan da Silva, Xi Chen, George F. S. Whitehead, John Maddock, Louise S. Natrajan, Meredydd Kippax-Jones, Dukula De Alwis Jayasinghe, Carlo Bawn, Daniil M. Polyukhov, Yinlin Chen, Vladimir P. Fedin, Sihai Yang, Martin Schröder   +15 more
doaj   +1 more source

Nanoparticle Shape Dictates Catalytic Performance in Selective Hydrogenation of Butadiene Over Au‐Pd Core‐Shell Nanoparticles

Advanced Functional Materials, EarlyView.
Controlling the exposed crystal facet of shape‐controlled Au‐Pd core‐shell catalysts though colloidal synthesis enhances their catalytic performance in the industrially relevant selective hydrogenation of butadiene. ABSTRACT Selective hydrogenation of butadiene is a critical step in purification of alkene feedstocks for polymer production and is ...
Marta Perxés Perich, Jan‐Willem Lankman, Petra E. de Jongh, Jessi E. S. van der Hoeven   +3 more
wiley   +1 more source

Interfacial Adsorption Engineering Enables a Highly Utilized Zinc Anode With 99.9% Coulombic Efficiency

Advanced Functional Materials, EarlyView.
When hydrated zinc ions are deposited onto Cu substrates at practical current densities, the modified Cu enables simultaneously compact zinc growth and suppressed hydrogen evolution. This regulatory effect originates from the superior adsorption of the modified Cu interface, which enhances zincophilicity and the hydrogen desorption barrier, thereby ...
Zhe Zhu, Xiaoqiao Liao, Yihao Long, Mengmeng Yang, Ibrahem O. Baibars, Ruiqi Song, Zhun Shi, Liang He, Chuan Zhao   +8 more
wiley   +1 more source

Dual‐Function Interface Engineering for δ‐Phase‐Free Crystallization Toward Efficient and Stable FAPbI3 Perovskite Solar Cells

Advanced Functional Materials, EarlyView.
This work presents a dual‐function interface engineering strategy using PEACl to suppress the formation of the non‐perovskite δ‐FAPbI3 phase at the critical SnO2 buried interface. This approach enables the direct crystallization of the photoactive α‐phase, yielding highly efficient and stable rigid (25.6%) and flexible perovskite solar cells with ...
Xiao Wu, Shengyuan Wang, Pok Fung Chan, Zhenyi Ni, Hengkai Zhang, Chun‐Jen Su, Junyi Zhu, Xinhui Lu   +7 more
wiley   +1 more source

Stability of Zr-Based UiO-66 Metal–Organic Frameworks in Basic Solutions

Although Zr-based metal–organic frameworks (MOFs) exhibit robust chemical and physical stability in the presence of moisture and acidic conditions, their susceptibility to nucleophilic attacks from bases poses a critical challenge to their overall ...
Seungheon Cha, Haein Kim, Jun Yeong Kim, Isaac Choi, Min Kim, Houng Kang, Jiwon Kang, Dopil Kim   +7 more
core   +1 more source

Dual‐Salt Carbothermal Shock Strategy Enabling Ultrafast and Sustainable Regeneration of Spent LiFePO4 Cathode Materials

Advanced Functional Materials, EarlyView.
Lithium iron phosphate (LFP) accounts for over 50% of the global cathode market, underscoring the need for efficient recycling and regeneration. We propose a dual‐salt carbothermal shock (CTS) strategy using LiI and NaI to in situ repair Li vacancies.
Yanjuan Li, Zhongou Yang, Junhui Cai, Yiran Li, Zhenzhen Wu, Zhouyang Long, Xiao Yan, Shanqing Zhang   +7 more
wiley   +1 more source

Dual‐Inductive and Programmable Switching: A New Paradigm in Ionic Interface‐Controlled Perovskite Memory

Advanced Functional Materials, EarlyView.
A fully programmable, dual‐inductive switchable halide perovskite memristor is demonstrated through precise BDAI2‐mediated interface engineering. This ion‐modulating layer suppresses stochastic filamentary growth, enabling stable, non‐filamentary switching via dynamic barrier modulation.
So‐Yeon Kim, Juan Bisquert
wiley   +1 more source

Exciton Binding Energy of Phosphorescent Emitter Molecules in Organic Light‐Emitting Diodes

Advanced Functional Materials, EarlyView.
Energy level alignment is key to efficient OLED design, yet determining LUMO energies remains challenging. A methodology based on field‐induced dissociation and kinetic Monte Carlo simulations is presented to extract LUMO energies of iridium‐based phosphorescent emitters from their exciton binding energy.
Hiroki Tomita, Lucas R. L. Norg, Patrick Diederen, Clint van Hoesel, Christ H. L. Weijtens, Peter A. Bobbert, Reinder Coehoorn   +6 more
wiley   +1 more source