Results 51 to 60 of about 89,492 (273)

Mass spectrometry based identification of AMP‐O‐Tris generated by Thermococcus onnurineus Cas10

FEBS Open Bio, EarlyView.
Isolated Thermococcus onnurineus Cas10 generates the noncanonical ATP‐derived product AMP‐O‐Tris while in Tris‐containing buffer as identified via mass spectrometry, revealing relaxed nucleophile selectivity under isolated conditions. These findings suggest that multiprotein Csm complex assembly restricts Cas10 reactivity toward canonical cyclic ...
Su‐Jin Lee, Ga Seul Lee, JinHan Kim, Kwang‐Hyun Park, Seong‐Ryung Go, Jeong Hee Moon, Eui‐Jeon Woo   +6 more
wiley   +1 more source

MOFganic Chemistry: Challenges and Opportunities for Metal-Organic Frameworks in Synthetic Organic Chemistry

, 2023
Metal-organic frameworks (MOFs) are porous, crystalline solids constructed from organic linkers and inorganic nodes that have been widely studied for applications in gas storage, chemical separations, and drug delivery.
Thomas, Hicks, Sijing, Meng, Bayu, Ahmad, Emily, Stacy, Phillip, Milner, Kaitlyn, Keasler   +5 more
core   +1 more source

Exceptional catalytic activity of oxygen evolution reaction via two-dimensional graphene multilayer confined metal-organic frameworks

Nature Communications, 2022
While metal-organic frameworks offer a diverse array of structural motifs for electrocatalysis, poor conductivity and mass permeability limit performances.
Siliu Lyu, Chenxi Guo, Jianing Wang, Zhongjian Li, Bin Yang, Lecheng Lei, Liping Wang, Jianping Xiao, Tao Zhang, Yang Hou   +9 more
doaj   +1 more source

Sudden anaerobization in Amphibacillus xylanus increases intracellular labile ferrous iron and inhibits cell growth

FEBS Open Bio, EarlyView.
Abruptly changing from aerobic to anaerobic conditions (sudden anaerobization) induced growth inhibition and a significant increase in intracellular labile ferrous iron in the aerotolerant anaerobe Amphibacillus xylanus. We found that free flavins mediate efficient electron transfer from NADH to ferric iron under anaerobic conditions, suggesting that ...
Shinya Kimata, Yoichi Sakai, Keisuke Tanaka, Etsuro Yoshimura, Ken Kitano, Morio Ishikawa, Tadahiro Nakamoto, Tsutomu Takayama, Hirofumi Inoue, Kaho Nomura, Tomonori Suzuki, Masataka Uchino, Akira Abe, Youichi Niimura   +13 more
wiley   +1 more source

Metal-organic frameworks induce hypergolic ignition of bulk metals

, 2021
We demonstrate the unprecedented ability to induce hypergolic behavior, i.e. rapid and spontaneous ignition upon contact with an oxidizer, in non-hypergolic metal fuels by blending them with hypergolic metal-organic frameworks (HMOFs).
Hatem, Titi, Joseph, Marrett, Olivier, Jobin, Étienne, Robert, Audrey, Moores, Tomislav, Friscic, Blaine, Fiss, Robin, Rogers, Cristina, Mottillo   +8 more
core   +1 more source

Modified reverse degree descriptors for combined topological and entropy characterizations of 2D metal organic frameworks: applications in graph energy prediction

Frontiers in Chemistry
Topological descriptors are widely utilized as graph theoretical measures for evaluating the physicochemical properties of organic frameworks by examining their molecular structures.
A. R. Abul Kalaam, A. Berin Greeni, Micheal Arockiaraj   +2 more
doaj   +1 more source

Retrosynthesis of multi-component metal−organic frameworks

Nature Communications, 2018
The crystal engineering of metal–organic frameworks has led to the construction of complex structures, but has yet to reach the same level of sophistication as organic synthesis.
Shuai Yuan, Jun-Sheng Qin, Jialuo Li, Lan Huang, Liang Feng, Yu Fang, Christina Lollar, Jiandong Pang, Liangliang Zhang, Di Sun, Ali Alsalme, Tahir Cagin, Hong-Cai Zhou   +12 more
doaj   +1 more source

UiO‐66 metal–organic frameworks in biomedicine: From structural tunability to bioimaging, photodiagnostics, and photodynamic cancer therapy

FEBS Open Bio, EarlyView.
UiO‐66(Zr) metal–organic frameworks are chemically stable, biocompatible, and highly tunable nanomaterials. Their modular structure enables controlled drug delivery, multimodal bioimaging, and light‐activated photodynamic therapy, supporting integrated diagnostic and therapeutic (theranostic) applications in cancer and biomedical research.
Veronika Huntošová, Grigorii Rakhalskii, Miroslav Almáši   +2 more
wiley   +1 more source

Polydopamine-Modified Metal–Organic Frameworks, NH2-Fe-MIL-101, as pH-Sensitive Nanocarriers for Controlled Pesticide Release

, 2020
Recently, metal–organic frameworks (MOFs) have become a dazzling star among porous materials used in many fields. Considering their intriguing features, MOFs have great prospects for application in the field of sustainable agriculture, especially ...
Chunli Xu, Hongjun Zhang, Shujun Niu, Qiliang Huang, Yongpan Shan, Muhammad Bilal, Lidong Cao, Huiping Chen   +7 more
core   +1 more source

Synthesis, Structural Versatility, Magnetic Properties, and I− Adsorption in a Series of Cobalt(II) Metal–Organic Frameworks with a Charge-Neutral Aliphatic (O,O)-Donor Bridge

, 2023
Four new metal–organic frameworks based on cobalt(II) salts and 1,4-diazabicyclo[2.2.2]octane N,N’-dioxide (odabco) were obtained. Their crystallographic formulae are [Co3(odabco)2(OAc)6] (1, OAc− = acetate), [Co(H2O)2(HCOO)2]· ...
Vladimir P. Fedin, Evgeniya V. Polyakova, Ksenia D. Abasheeva, Pavel A. Demakov, Alexander N. Lavrov, Danil N. Dybtsev   +5 more
core   +1 more source