Results 31 to 40 of about 410,888 (329)

Post-synthetic pillaring enhances metal–organic framework capacitance

Communications Chemistry, 2022
Electrically conductive two-dimensional metal–organic frameworks have emerged as promising materials for electronic and energy storage devices, but their stacked nature offers limited accessibility to the framework pores.
Victoria Richards
doaj   +1 more source

Defect‐Engineered Metal–Organic Frameworks [PDF]

Angewandte Chemie International Edition, 2015
AbstractDefect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and catalysis, but also in controlling more challenging physical characteristics such as band gap as well as magnetic and electrical/conductive properties.
Fang, Zhenlan, Bueken, Bart, De Vos, Dirk E., Fischer, Roland A.   +3 more
openaire   +3 more sources

Exploring lanthanide doping in UiO-66 : a combined experimental and computational study of the electronic structure [PDF]

, 2018
Lanthanide-based metal organic frameworks show very limited stabilities, which impedes their use in applications exploiting their extraordinary electronic properties, such as luminescence and photocatalysis.
De Vos, Arthur, Hendrickx, Kevin, Joos, Jonas, Lejaeghere, Kurt, Poelman, Dirk, Smet, Philippe, Van Der Voort, Pascal, Van Speybroeck, Veronique   +7 more
core   +2 more sources

Metal–Organic Framework Materials for Electrochemical Supercapacitors

Nano-Micro Letters, 2022
Exploring new materials with high stability and capacity is full of challenges in sustainable energy conversion and storage systems. Metal–organic frameworks (MOFs), as a new type of porous material, show the advantages of large specific surface area ...
Ziwei Cao, Roya Momen, Shusheng Tao, Dengyi Xiong, Zirui Song, Xuhuan Xiao, Wentao Deng, Hongshuai Hou, Sedat Yasar, Sedar Altin, Faith Bulut, Guoqiang Zou, Xiaobo Ji   +12 more
doaj   +1 more source

Dynamic interplay between defective UiO‐66 and protic solvents in activated processes [PDF]

, 2019
UiO-66, composed by Zr-oxide inorganic bricks [Zr-6(mu(3)-O)(4)(mu(3)-OH)(4)] and organic terephthalate linkers, is one of the most studied metal-organic frameworks (MOFs) due to its exceptional thermal, chemical, and mechanical stability.
Caratelli, Chiara, Hajek, Julianna, Meijer, Evert Jan, Van Speybroeck, Veronique, Waroquier, Michel   +4 more
core   +2 more sources

Metal–Organic Frameworks in Agriculture

ACS Applied Materials & Interfaces, 2022
Agrochemicals, which are crucial to meet the world food qualitative and quantitative demand, are compounds used to kill pests (insects, fungi, rodents, or unwanted plants). Regrettably, there are some important issues associated with their widespread and extensive use (e.g., contamination, bioaccumulation, and development of pest resistance); thus, a ...
Sara Rojas, Antonio Rodríguez-Diéguez, Patricia Horcajada   +2 more
openaire   +3 more sources

Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester. [PDF]

, 2019
Sorbent-assisted water harvesting from air represents an attractive way to address water scarcity in arid climates. Hitherto, sorbents developed for this technology have exclusively been designed to perform one water harvesting cycle (WHC) per day, but ...
Diercks, Nicolas J, Fathieh, Farhad, Glover, T Grant, Hanikel, Nikita, Kapustin, Eugene A, Lyu, Hao, Prévot, Mathieu S, Wang, Haoze, Yaghi, Omar M   +8 more
core   +3 more sources

Cooperative Carbon Dioxide Adsorption in Alcoholamine- and Alkoxyalkylamine-Functionalized Metal-Organic Frameworks. [PDF]

, 2020
A series of structurally diverse alcoholamine- and alkoxyalkylamine-functionalized variants of the metal-organic framework Mg2 (dobpdc) are shown to adsorb CO2 selectively via cooperative chain-forming mechanisms.
Forse, Alexander C, Kim, Eugene J, Lee, Jung-Hoon, Long, Jeffrey R, Mao, Victor Y, McGuirk, C Michael, Milner, Phillip J, Neaton, Jeffrey B, Porter-Zasada, Leo B, Reimer, Jeffrey A, Siegelman, Rebecca L   +10 more
core   +2 more sources

Metal–Organic Framework Nanoparticles

Advanced Materials, 2018
AbstractDue to their well‐defined 3D architectures, permanent porosity, and diverse chemical functionalities, metal–organic framework nanoparticles (MOF NPs) are an emerging class of modular nanomaterials. Herein, recent developments in the synthesis and postsynthetic surface functionalization of MOF NPs that strengthen the fundamental understanding of
Shunzhi Wang, C. Michael McGuirk, Andrea d'Aquino, Jarad A. Mason, Chad A. Mirkin   +4 more
openaire   +3 more sources

Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal-organic framework [PDF]

, 2015
Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal-organic framework (MOF).
Cliffe, Matthew J., Coudert, Francois-Xavier, Goodwin, Andrew L., Hill, Joshua A., Murray, Claire A.   +4 more
core   +4 more sources