Dynamic interplay between defective UiO‐66 and protic solvents in activated processes [PDF]
, 2019 UiO-66, composed by Zr-oxide inorganic bricks [Zr-6(mu(3)-O)(4)(mu(3)-OH)(4)] and organic terephthalate linkers, is one of the most studied metal-organic frameworks (MOFs) due to its exceptional thermal, chemical, and mechanical stability.
Caratelli, Chiara +4 more
core +2 more sources
Docking in Metal-Organic Frameworks [PDF]
Science, 2009 MOFs with Guest Rooms Metal organic framework (MOF) solids typically boast large pores in their crystal lattices that can accommodate molecular guests and are useful as compact media for gas storage. However, guest binding has generally relied upon nonspecific interactions with the framework components.
Li, QW Li, Qiaowei +8 more
openaire +4 more sources
Early stages of phase selection in MOF formation observed in molecular Monte Carlo simulations [PDF]
, 2019 Metal-organic frameworks (MOF) comprising metal nodes bridged by organic linkers show great promise because of their guest-specific gas sorption, separation, drug-delivery, and catalytic properties.
Cessford, Naomi F. +3 more
core +1 more source
Cooperative Carbon Dioxide Adsorption in Alcoholamine- and Alkoxyalkylamine-Functionalized Metal-Organic Frameworks. [PDF]
, 2020 A series of structurally diverse alcoholamine- and alkoxyalkylamine-functionalized variants of the metal-organic framework Mg2 (dobpdc) are shown to adsorb CO2 selectively via cooperative chain-forming mechanisms.
Forse, Alexander C +10 more
core +2 more sources
Functionalised metal-organic frameworks: a novel approach to stabilising single metal atoms [PDF]
, 2017 We have investigated the potential of metal-organic frameworks for immobilising single atoms of transition metals using a model system of Pd supported on NH2-MIL-101(Cr).
Borgschulte, A. +9 more
core +1 more source
Properties of Metal-Doped Covalent Organic Frameworks and Their Interactions with Sulfur Dioxide
Journal of Chemistry, 2018 Covalent organic frameworks are unique for their highly open architecture and attractive for use as promising gas adsorption and storage carriers. In this work, density functional theory calculations have been performed to investigate the properties of ...
Ju Wang +4 more
doaj +1 more source
Selective gas capture via kinetic trapping
, 2016 Conventional approaches to the capture of CO_2 by metal-organic frameworks focus on equilibrium conditions, and frameworks that contain little CO_2 in equilibrium are often rejected as carbon-capture materials. Here we use a statistical mechanical model,
Kundu, Joyjit +3 more
core +1 more source
Flexibility in metal–organic frameworks : a basic understanding [PDF]
, 2019 Much has been written about the fundamental aspects of the metal-organic frameworks (MOFs). Still, details concerning the MOFs with structural flexibility are not comprehensively understood.
Aljammal, Nour +4 more
core +1 more source
Metal Organic Frameworks: Synthesis and Application
Molecules, 2020 The concept of metal−organic frameworks (MOFs) was first introduced in 1990; nowadays they are among the most promising novel materials [...]
Victoria F. Samanidou +1 more
doaj +1 more source
Acoustic Properties of Metal-Organic Frameworks
Research, 2021 Metal-organic frameworks (MOFs) have attracted significant attention in the past two decades due to their diverse physical properties and associated functionalities.
Zhi-Gang Li +6 more
doaj +1 more source