Results 81 to 90 of about 251,389 (313)

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

Modulating Two‐Photon Absorption in a Pyrene‐Based MOF Series: An In‐Depth Investigation of Structure–Property Relationships

open access: yesAdvanced Functional Materials, EarlyView.
This study investigates H4TBAPy‐based metal–organic frameworks (MOFs) ‐ NU‐1000, NU‐901, SrTBAPy, and BaTBAPy ‐ for multiphoton absorption (MPA) performance. It observes topology‐dependent variations in the 2PA cross‐section, with BaTBAPy exhibiting the highest activity.
Simon N. Deger   +10 more
wiley   +1 more source

Insights into Surface Interactions between Metal Organic Frameworks and Gases during Transient Adsorption and Diffusion by In-Situ Small Angle X-ray Scattering

open access: yesMembranes, 2016
The fabrication of molecular gas sieving materials with specific affinities for a single gas species and able to store large quantities of materials at a low or atmospheric pressure is desperately required to reduce the adverse effects of coal and oil ...
Ludovic F. Dumée   +3 more
doaj   +1 more source

Sustainable metal-organic framework based paper sheet as wallpaper for passive indoor moisture control

open access: yesEnergy and Buildings
Passive indoor moisture control is a meaningful way to reduce HVAC operation and improve building energy efficiency. Metal-organic frameworks (MOFs) have been considered one of the most promising sorbent materials for passive indoor moisture control. However, the powder form of MOF is challenging to use in the built environment. Typical shaping methods
Dong Ding   +2 more
openaire   +2 more sources

Near‐Infrared Emitting Lanthanide Catecholate Giant Single Crystals – Morphology Control and Photon Down‐Conversion

open access: yesAdvanced Functional Materials, EarlyView.
Controlled syntheses of lanthanide coordination polymers based on the dihydroxybenzoquinone (DHBQ) organic linker afforded large single crystals of Ln‐DHBQ CPs (Ln = Yb, Nd). A novel structural variant of Yb‐DHBQ is identified by means of single crystal diffraction analysis.
Marina I. Schönherr   +7 more
wiley   +1 more source

Quinoline beta-lactams by Rh(II)-catalyzed highly steroselective intramolecular carbene insertion into a carbon-hydrogen bond [PDF]

open access: yes, 2005
A convenient synthesis of tricyclic β-lactams by chemo- and diastereoselective intramolecular CH insertion of metal carbenes generated by dirhodium(II) tetraacetate catalyzed decomposition of α-diazoamides 1a-c is reported.
Muroni, Daniele, Saba, Antonio
core  

Surface plasmon-mediated far-field emission of laser dye solutions

open access: yes, 2010
Angle-resolved reflection and emission spectra of metal gratings consisting of sub-wavelength grooves and immersed into rhodamine B and rhodamine 19 solutions are presented.
Fick, Jochen, Geiger, Carola
core   +3 more sources

The thermal visualisation of latent fingermarks on metallic surfaces [PDF]

open access: yes, 2011
Recent published research has lead to improved techniques for recovering latent fingermarks from metallic surfaces. The present study corroborates and extends some of the work carried out by Bond [1], [2] and [3], but an alternative mechanism is proposed
O’Connor, D., Wightman, Graham
core   +3 more sources

Composites of Shellac and Silver Nanowires as Flexible, Biobased, and Corrosion‐Resistant Transparent Conductive Electrodes

open access: yesAdvanced Functional Materials, EarlyView.
Shellac, a centuries‐old natural resin, is reimagined as a green material for flexible electronics. When combined with silver nanowires, shellac films deliver transparency, conductivity, and stability against humidity. These results position shellac as a sustainable alternative to synthetic polymers for transparent conductors in next‐generation ...
Rahaf Nafez Hussein   +4 more
wiley   +1 more source

Elaborating the knowledge structure and emerging research in the utilization of metal–organic formwork in engineering applications: A scientometric analysis from 2004 to 2024

open access: yesCleaner Materials
Metal–organic frameworks (MOFs) have emerged as versatile materials with broad applications in engineering, from energy storage and environmental remediation to biomedical and sensing technologies.
Mohammed H. Alzard   +2 more
doaj   +1 more source

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