Results 31 to 40 of about 21,892 (259)
Journal of the Turkish Chemical Society, Section A: Chemistry, 2018 The purpose has been to achieve a controlled ring-opening polymerization of ɛ-caprolactone, resulting in polymers with desirable properties such as high molecular weight, low polydispersity index, and highly regio-/stereo regular forms.
Yağmur Gökalp, Asgar Kayan
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Use of metal catalysts bearing Schiff base macrocycles for the ring opening polymerization (ROP) of cyclic esters [PDF]
, 2017 © 2017 by the authors. Schiff base macrocycles are emerging as useful scaffolds for binding two or more catalytic metals in close proximity. Such coordination chemistry allows for the evaluation of potentially beneficial catalytic cooperative effects. In
Redshaw, Carl
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Scientific Reports, 2023 Elucidating the complex degradation pathways and formed decomposition products of the electrolytes in Li-metal batteries remains challenging. So far, computational studies have been dominated by studying the reactions at inert Li-metal surfaces.
Liang-Ting Wu +5 more
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Vanadium(v) phenolate complexes for ring opening homo- and co-polymerisation of ε-caprolactone, L-lactide and rac-lactide [PDF]
, 2015 The vanadyl complexes [VO(OtBu)L¹ ] (1) and {[VO(OiPr)]₂ (μ-p-L²ᵖ)} (2) {[VO(OR)]₂ (μ-p-L²ᵐ )} (R = iPr 3, tBu 4) have been prepared from [VO(OR)₃ ] (R = nPr, iPr or tBu) and the respective phenol, namely 2,2′-ethylidenebis(4,6-di-tert-butylphenol) (L¹ ...
Al-Khafaji, Yahya +6 more
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Double Metal Alkoxides / Heterometallic Alkoxides
, 1995 Heterometallic alkoxides are those alkoxides having two or more different metals linked via bridging alkoxy groups, via oxo-groups or sometimes metal-metal bonding. The large majority of heterometallic alkoxides corresponds to derivatives in which one of the metals is either an alkali or alkaline earth metal.
Kapoor, Ramesh, Arkles, Barry
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Nanocomposite organomineral hybrid materials. Part 3
Нанотехнологии в строительстве, 2016 The paper addresses the issues of alkoxide method of sol-gel synthesis and non-hydrolytic method of sol-gel synthesis and colloidal method of sol-gel synthesis.
KUDRYAVTSEV Pavel Gennadievich +1 more
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Metal alkoxides: Models for metal oxides: Alkoxide ligands in early transition metal organometallic chemistry [PDF]
, 1990 An effort was made to compare and contrast the reactivity of trialkylsiloxide vs tert-butoxide supported dinuclear centers, and an initiative aimed at studying the syntheses of polynuclear hydridoalkoxides and their reactions has been implemented.
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Acta Crystallographica Section E, 2010 The anion of the title salt, (C10H10NO)[ZnBr2(C10H8NO)]·CH3OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hydroxyquinoline ligand.
Seik Weng Ng +2 more
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The ammonolysis of esters in liquid ammonia [PDF]
, 2013 The rates of ammonolysis of alkyl benzoate and phenylacetate esters in liquid ammonia increase with the acidity of the leaving group alcohol and show relatively large Brønsted βlg values of −1.18 and −1.34, respectively, when plotted against the aqueous ...
Atherton, John +2 more
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Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II)
Acta Crystallographica Section E, 2008 The title compound, [Cu(C5H10NO3)2], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2 ...
Brian W. Skelton +3 more
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