New Water Oxidation Mechanism in Photosystem II Resolves Major Experimental Controversies
In Photosystem II Oxygen Evolving Complex, we discovered the O3‐O6 peroxide at lower energy. Assignment of the O3 ligated by histidine (His337) as a slow exchanging substrate and its coupling with O6 give the O─O bond formation mechanism most consistent with all currently available experimental data. Proposal shows how protein environment can steer the
Yulia Pushkar
wiley +2 more sources
Block CO<sub>2</sub>-Polycarbonates: Tunable Chain Extension with Zn(II) Carboxylates. [PDF]
Poon KC +4 more
europepmc +1 more source
Piezoelectric Nanocomposite Hydrogel for Wireless Neural Stimulation and Tissue Augmentation
A cell/tissue supporting piezoelectric hydrogel system (PZ‐gel) that incorporates ferroelectric, pyroelectric, and piezoelectric ceramic material barium titanate into an alginate/carboxymethyl chitosan hydrogel. The PZ‐gel can be sonoactivated for wireless neural cell and tissue stimulation, with the potential to be used as a stimulatory cell substrate
Mohammad Mohammadi +3 more
wiley +1 more source
Structural and Functional Siderophore Remodeling by Enzymatic Delipidation
A surprising functional switch in bacterial siderophores was discovered through genome mining and the analysis of environmental and pathogenic Pandoraea species. Pandorachelin B, a lipocyclopeptide that promotes swarming motility, is cleaved by a specialized acylase, yielding a ring‐contracted, homodetic cyclopeptide, pandorachelin A, which exhibits ...
Elena Herzog +5 more
wiley +2 more sources
Ligand-to-Metal Charge Transfer of Ag(II) CF<sub>2</sub>X Carboxylates: Quantum Yield and Electrophotocatalytic Arene Fluoroalkylation Tuned by X. [PDF]
Campbell BM +5 more
europepmc +1 more source
Solvent induced rapid modulation of micro/nano structures of metal carboxylates coordination polymers: mechanism and morphology dependent magnetism. [PDF]
Liu K +7 more
europepmc +1 more source
Solvent Hydrogen Bonding Determines Adsorption Geometry of Trimesic Acid on Cu
Water reorients adsorbate molecules. Combined tip‐enhanced Raman spectroscopy, density functional theory and molecular dynamics simulations reveal the adsorption geometry of trimesic acid on Cu. Subtle adsorbate–substrate–solvent energy differences due to hydrogen bonding dictate molecular orientation at solid/liquid and solid/gas interfaces, providing
Anusha Lalitha +4 more
wiley +2 more sources
Heterometallic Pyrazolate Bridge Complexes [PhenPd <sub><i>x</i></sub> (μ-dmpz) <i><sub>n</sub></i> M(OOCR)<sub>2</sub>] (M = Co<sup>II</sup>, Cu<sup>II</sup>, Zn<sup>II</sup>) via Coordinated Hdmpz Deprotonation. [PDF]
Uvarova MA +3 more
europepmc +1 more source
Graphene-Coated Metal Oxide Nanocrystals (M <sub><b><i>x</i></b> </sub> O <sub><b><i>y</i></b> </sub> @C) Form during the Liquid-Phase Thermal Decomposition of Metal Oleates. [PDF]
Masterson CM +7 more
europepmc +1 more source
Room-temperature photoluminescence in monocarboxylate-protected silver nanoclusters via steric hindrance-induced interfacial structure locking. [PDF]
Jiang W +6 more
europepmc +1 more source

