Results 141 to 150 of about 8,724 (213)

Natural Anionic Interfacial Reconstruction for Suppressing Pitting Corrosion Enables Durable Seawater Zinc‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
In situ electrochemically induced molecular sieve‐alginate interface layer can suppress chloride‐induced pitting corrosion, hydrogen evolution, and dendrite growth, while regulating zinc ion transport and deposition, thereby protecting the zinc anode in seawater electrolyte.
Yunpeng Zhong   +7 more
wiley   +1 more source

Nickel‐Free Synthesis of Poly(pyrene‐4,5,9,10‐tetraone) for Sodium‐based Batteries: Insights into Electrode Architecture and Reversible Na‐ion Insertion

open access: yesAdvanced Energy Materials, EarlyView.
A nickel‐free and practical synthesis strategy to poly(pyrene tetraone) and its integration with a percolated CNTs/Ketjen Black network enables stable cycling and efficient energy storage in a sodium‐based batteries. This work demonstrates how controlling polymer structure and electrode architecture improves ion transport and mitigates dissolution in ...
Md. Adil   +9 more
wiley   +1 more source

Palladacarboxamide Capping Reagents for Carbon Isotope Labeling and Pharmaceutical Diversification

open access: yesAngewandte Chemie, EarlyView.
Herein, we present a method for carbon isotope labeling of arylamides via the coupling of air‐stable palladium carboxamide complexes and boronic ester/acids. A wide variety of functionalized boronic esters and acids have been coupled with simple palladium carboxamides complexes.
Daniel V. Hoffmann   +8 more
wiley   +1 more source

A New Metal‐Ester Bonding Motif for the Synthesis of Hybrid Molecular Catalysts on Metal Oxide Supports Leads to Tunable Reactivity

open access: yesAngewandte Chemie, EarlyView.
This work reports a new metal–ester bonding strategy for anchoring molecular catalysts to metal oxide supports, achieving exceptionally high surface loadings. Catalyst reactivity is predictably tuned by the support's properties, enabling control over electronic behavior and reaction pathways, thus opening new possibilities for designing highly ...
Joseph J. Kuchta III   +7 more
wiley   +1 more source

Energetics of carboxylate-metal bonds in polymetallic rings. [PDF]

open access: yesChem Commun (Camb)
Geue N   +6 more
europepmc   +1 more source

New Water Oxidation Mechanism in Photosystem II Resolves Major Experimental Controversies

open access: yesAngewandte Chemie, EarlyView.
In Photosystem II Oxygen Evolving Complex, we discovered the O3‐O6 peroxide at lower energy. Assignment of the O3 ligated by histidine (His337) as a slow exchanging substrate and its coupling with O6 give the O─O bond formation mechanism most consistent with all currently available experimental data. Proposal shows how protein environment can steer the
Yulia Pushkar
wiley   +1 more source

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