Results 11 to 20 of about 8,724 (213)

Synthesis and characterization of novel oxo-bridged, trinuclear mixed-metal complexes of Cr(III) and Fe(III) [PDF]

Journal of the Serbian Chemical Society, 2009
Two new heterotrinuclear p-chlorobenzoates, [Fe2CrO(C7H4O2Cl)6(py)3]NO3 (1) and [Cr2FeO(C7H4O2Cl)6(py)3]NO3 (2) were prepared as nitrate salts and characterized by elemental analyses (CHN), spectroscopic (infrared, electronic) studies and atomic ...
HAMAN TAVAKKOLI, IMAN KHOSRAVI, MOHAMMAD YAZDANBAKHSH   +2 more
doaj   +3 more sources

Bioinspired trimesic acid anchored electrocatalysts with unique static and dynamic compatibility for enhanced water oxidation

Nature Communications, 2023
Layered double hydroxides are promising candidates for the electrocatalytic oxygen evolution reaction. Unfortunately, their catalytic kinetics and long-term stabilities are far from satisfactory compared to those of rare metals.
Xiaojing Lin, Zhaojie Wang, Shoufu Cao, Yuying Hu, Siyuan Liu, Xiaodong Chen, Hongyu Chen, Xingheng Zhang, Shuxian Wei, Hui Xu, Zhi Cheng, Qi Hou, Daofeng Sun, Xiaoqing Lu   +13 more
doaj   +1 more source

Electron-Induced Decomposition of Different Silver(I) Complexes: Implications for the Design of Precursors for Focused Electron Beam Induced Deposition

Nanomaterials, 2022
Focused electron beam induced deposition (FEBID) is a versatile tool to produce nanostructures through electron-induced decomposition of metal-containing precursor molecules. However, the metal content of the resulting materials is often low.
Petra Martinović, Markus Rohdenburg, Aleksandra Butrymowicz, Selma Sarigül, Paula Huth, Reinhard Denecke, Iwona B. Szymańska, Petra Swiderek   +7 more
doaj   +1 more source

Synthesis, characterization, thermal behavior and antimicrobial activity of 3-methyl benzoate complexes of transition metal with hydrazine

Bulletin of the Chemical Society of Ethiopia, 2016
Reaction of the ligands, 3-methyl benzoic acid (mbH) and hydrazine with transition metal ions form the complexes of formulae, [M(N2H4)2(mb)2].H2O where M = Co(II) and Zn(II) at pH = 5-6, [M(N2H4)n(mb)2].xH2O where M = Ni(II), n = 2, x = 0 at pH = 5 and
S. Mohanapriya, Muthukumaran Muthukumaran, S. Vairam   +2 more
doaj   +1 more source

In situ grown oxygen-vacancy-rich copper oxide nanosheets on a copper foam electrode afford the selective oxidation of alcohols to value-added chemicals

Communications Chemistry, 2022
Converting low-molecular-weight aliphatic alcohols like methanol and ethanol into value-added chemicals such as carboxylates in electrolytic cells offers low operating costs, but non-noble-metal catalysts often bring about low selectivities and ...
Mustafa Khan, Asima Hameed, Abdus Samad, Talifhani Mushiana, Muhammad Imran Abdullah, Asma Akhtar, Raja Shahid Ashraf, Ning Zhang, Bruno G. Pollet, Udo Schwingenschlögl, Mingming Ma   +10 more
doaj   +1 more source

Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Molecules, 2022
Metal-organic frameworks [M2(2-I-bdc)2bpe] (M = Zn(II) (1), Co(II) (2), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry.
Alexander S. Zaguzin, Taisiya S. Sukhikh, Ilyas F. Sakhapov, Vladimir P. Fedin, Maxim N. Sokolov, Sergey A. Adonin   +5 more
doaj   +1 more source

Selective reduction and homologation of carbon monoxide by organometallic iron complexes

Nature Communications, 2018
Metal-mediated activation of CO for C-C coupling reactions is a valuable approach to carbon monoxide valorization. Here, the authors use low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines and ...
Helen R. Sharpe, Ana M. Geer, Laurence J. Taylor, Benjamin M. Gridley, Toby J. Blundell, Alexander J. Blake, E. Stephen Davies, William Lewis, Jonathan McMaster, David Robinson, Deborah L. Kays   +10 more
doaj   +1 more source

Two-step analytical procedure for the characterization and quantification of metal soaps and resinates in paint samples

Heritage Science, 2018
Metal soaps and resinates are known to be spontaneously formed in artistic paintings, as a product of the reaction between aliphatic and terpenoid acids released by hydrolysis and oxidation of the organic media and certain cations contained in some ...
Jacopo La Nasa, Anna Lluveras-Tenorio, Francesca Modugno, Ilaria Bonaduce   +3 more
doaj   +1 more source

Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior

Inorganics, 2023
Two new coordination polymers based on Zn(II) and 2,5-diiodoterephthalate—{[Zn(2,5-I-bdc)bpe}] (1) and {[Zn(2,5-I-bdc)bpen}] (2)—were synthesized and characterized.
Alexander S. Zaguzin, Taisiya Sukhikh, Maxim N. Sokolov, Vladimir P. Fedin, Sergey A. Adonin   +4 more
doaj   +1 more source

Carboxylic acid-modified metal oxide catalyst for selectivity-tunable aerobic ammoxidation

Nature Communications, 2018
Precisely controlling the surface properties of base-metal oxide catalysts to tune the reaction selectivity remains a challenge. Here, the authors show that a green modification of manganese oxide surface with carboxylates can be used to tune the ...
Xiuquan Jia, Jiping Ma, Fei Xia, Yongming Xu, Jin Gao, Jie Xu   +5 more
doaj   +1 more source