Results 41 to 50 of about 3,163,959 (346)

Ab initio study of the mechanism of carboxylic acids cross-ketonization on monoclinic zirconia via condensation to beta-keto acids followed by decarboxylation [PDF]

open access: yes, 2017
Catalytic mechanism of acetic and isobutyric acids mixture conversion into two symmetrical and one cross-ketone product on monoclinic zirconia (111) surface was extensively modeled by Density Functional Theory for periodic structures.
Bishop, Marc D.   +3 more
core   +2 more sources

Rethinking enrichments of trace element in low-rank coals: Preliminarily quantifying the effectiveness of local structure to stabilize humates

open access: yesEnergy Exploration & Exploitation, 2018
Trace element enrichment in coals has increasingly been focused in the community of coal geochemistry. To research the enrichment mechanism of trace element in coals on molecular/atomic scale is an important complement of field investigations, but ...
Le-Cai Xing   +7 more
doaj   +1 more source

Pyrazoles and imidazoles as ligands. XV. preparation, spectra and magnetic properties of di-μ-hydroxo-bis- [di(2-methylimidazole)copper(II)] diperchlorate dihydrate [PDF]

open access: yes, 1971
The preparation of the title compound is reported from Cu(ClO4)2, 2-methylimidazole and a small amount of water in ethanol solution. The compound consists of dimeric units [(2MIz)2Cu(OH)]22+, to which two perchlorate anions and two molecules of water are
Knetsch, D.   +2 more
core   +2 more sources

Carboxylate-Based Metal-Organic Frameworks

open access: yes, 2023
Metal–organic frameworks (MOFs) are a uique class of coordination polymers consist of inorganic metal ions or clusters, known as secondary building units (SBUs), interconnected by organic linkers. Their remarkable properties, such as large surface areas, high porosities, high adaptability, and diverse functionalities, have made them popular and enabled
openaire   +2 more sources

Thermo-Responsivity of the Polyacrylate-Adsorbed Metal Cation and its Hydration Structure

open access: yesAdsorption Science & Technology, 2008
The thermo-responsive phase behaviour of the sodium salt of poly(acrylic acid) (PAA) was studied when its counter-ion was exchanged for a series of metal cations (PAA–metal cation complexes).
Yoshimi Seida   +3 more
doaj   +1 more source

Corrosion behaviour of brazed multilayer material AA4343/AA3003/AA4343: Influence of coolant parameters [PDF]

open access: yes, 2007
This paper is the second part of a work devoted to corrosion in brazed AA4343/AA3003/AA4343 materials on the water side of automotive heater cores. In the first part of the study [S. Tierce, N.Pébère, C. Blanc, C. Casenave, G. Mankowski, H.
Blanc, Christine   +5 more
core   +4 more sources

The synergistic influence of metal cations on the drying and viscosity of linseed oil assessed by means of model samples containing synthesised metal carboxylates

open access: yesHeritage Science
The recent multi-analytical study carried out on the Van Eyck’s Ghent Altarpiece showed the simultaneous presence of several kinds of metal carboxylates in oil-rich glaze layers.
S. Kirkpatrick   +3 more
doaj   +1 more source

MIXED-METAL COMPLEXES OF RUTHENIUM(II,III) CARBOXYLATE AND TETRACYANIDOPLATINATE(II) [PDF]

open access: yesChemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2015
Mixed-metal complexes constructed from dinuclearruthenium(II,III) carboxylates and tetracyanidoplatinate(II), [{Ru2(O2CCH3)4}2Pt(CN)4]•2H2O (1) and [{Ru2{O2CC(CH3)3}4}2Pt(CN)4]•2H2O (2), were synthesized and characterized by elemental analysis and IR and
Masahiro Mikuriya   +5 more
doaj  

Nanoporous Frameworks with High Porosity and Unexpected Rigid Framework Topologies Based on Odd‐Numbered Ring‐Expanded Linkers

open access: yesSmall Science, 2023
Two tetracarboxylic linkers containing seven‐membered rings are synthesized and utilized in metal–organic framework (MOF) syntheses, leading to the two new compounds DUT‐184 and DUT‐193.
Bodo Felsner   +5 more
doaj   +1 more source

Removal of Copper (II) and Lead (II) from hydrometallurgical effluent onto cellulose nanocomposites: mechanistic and Levenberg-Marquardt in Artificial Neural Network modelling

open access: yesEQA, 2023
A well-designed adsorption system should meet the requirements for high efficiency while remaining cost and time effective. nanocellulose materials have a proven track record as viable adsorbent alternatives.
Musamba Banza, Hilary Rutto
doaj   +1 more source

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