Results 81 to 90 of about 3,163,959 (346)

Selective Benzene Capture by Metal‐Organic Frameworks

open access: yesAdvanced Functional Materials, EarlyView.
Metal‐organic frameworks (MOFs) hold significant potential for capturing benzene from air emissions and hydrocarbon mixtures in liquid phases. This capability stems from their precisely engineered structures, versatile chemistries, and diverse binding interactions.
Zongsu Han   +4 more
wiley   +1 more source

Poly[[tetraaqua(μ3-4-hydroxypyridine-2,6-dicarboxylato)di-μ2-oxalato-dipraseodymium(III)] 4.29-hydrate]

open access: yesIUCrData
The coordination polymer of crystal formula [PrIII2(C7H2NO5)(C2O4)2(H2O)4]·4.29H2O or [PrIII2(HCAM)(ox)2(H2O)4]·4.29H2O was synthesized from praseodymium(III) nitrate in water using chelidamic acid (H3CAM) and oxalic acid (H2ox).
Aaqib Khurshid   +2 more
doaj   +1 more source

A breathing zirconium metal-organic framework with reversible loss of crystallinity by correlated nanodomain formation [PDF]

open access: yes, 2016
The isoreticular analogue of the metal-organic framework UiO-66(Zr), synthesized with the flexible trans-1,4-cyclohexanedicarboxylic acid as linker, shows a peculiar breathing behavior by reversibly losing long-range crystalline order upon evacuation ...
Bueken, Bart   +12 more
core   +1 more source

Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76)

open access: yesAdvanced Functional Materials, EarlyView.
Luminescent MOF‐76 materials based on Eu(III) and mixed Eu(III)/Y(III) show rapid and reversible changes in emission intensity in response to O2 with very short response times. The effect is based on triplet quenching of the linker ligands that act as photosensitizers. Average emission lifetimes of a few milliseconds turn out to be mostly unaffected by
Zhenyu Zhao   +5 more
wiley   +1 more source

Influence of Titanium Oxide Pillar Array Nanometric Structures and Ultraviolet Irradiation on the Properties of the Surface of Dental Implants: A Pilot Study [PDF]

open access: yes, 2019
Aim: Titanium implants are commonly used as replacement therapy for lost teeth and much current research is focusing on the improvement of the chemical and physical properties of their surfaces in order to improve the osseointegration process. TiO2, when
Barranco Quero, Ángel   +5 more
core   +1 more source

Electroactive Metal–Organic Frameworks for Electrocatalysis

open access: yesAdvanced Functional Materials, EarlyView.
Electrocatalysis is crucial in sustainable energy conversion as it enables efficient chemical transformations. The review discusses how metal–organic frameworks can revolutionize this field by offering tailorable structures and active site tunability, enabling efficient and selective electrocatalytic processes.
Irena Senkovska   +7 more
wiley   +1 more source

Synthesis, Characterization, Semiempirical and Biological Activities of Organotin(IV) Carboxylates with 4-Piperidinecarboxylic Acid

open access: yesBioinorganic Chemistry and Applications, 2014
Organotin (IV) carboxylates with the general formulae R2Sn(Cl)L [R = Me (1), n-Bu (2), Ph (3)] and R3SnL [R = Me (4), Ph (5)] have been synthesized by the reaction of 4-piperidinecarboxylic acid (HL) with KOH and R2SnCl2 (R = Me, n-Bu, Ph)/R3SnCl (R = Me,
Shabbir Hussain   +5 more
doaj   +1 more source

Development of Greener D-Metal Inorganic Crosslinkers for Polymeric Gels Used in Water Control in Oil and Gas Applications

open access: yesEnergies, 2020
Crosslinkable polymers, such as polyacrylamide (PAM), are widely applied for water control in oil and gas reservoirs. Organic and inorganic crosslinkers are used to formulate a gel with PAM.
Hassan I. Nimir   +2 more
doaj   +1 more source

Cross-Selectivity in the Catalytic Ketonization of Carboxylic Acids [PDF]

open access: yes, 2015
A mixture of acetic and 2-methylpropanoic (isobutyric) acids representing non-branched and branched acids, respectively, was catalytically converted to a mixture of ketones in a set of statistically designed experiments (DOE).
Deraddo, Joseph   +3 more
core   +2 more sources

On‐Surface Indigo‐Based Bimolecular Coordination Networks with Programmable Regular or Vitreous Structure

open access: yesAdvanced Functional Materials, EarlyView.
A previously unreported coordination motif stabilising single Fe atoms by indigo chelation and pyridyl coordination on Au(111) has been revealed. By using planar tritopic pyridyl linkers (TPyB), extended 2D porous networks of indigo3(TPyB)2Fe6 form. These networks can be crystalline or vitreous and offer an environment where individual coordination ...
Hongxiang Xu   +9 more
wiley   +1 more source

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