Results 51 to 60 of about 8,361 (290)

Polarizable Vanadium Dipoles Promote Water Dissociation on Vanadium‐Based Metal Organic Framework

open access: yesAdvanced Functional Materials, EarlyView.
The polarization of unpaired V 3d electrons weakens the H─O bond to improve water dissociation by the dual Vδ+:O─H and Pλ−:H─O coupling hydrogen bonds formation and relaxation. P@V‐MOF electrocatalyst shows low overpotentials (94 mV in acid, 178 mV in neutral, and 77 mV in alkaline solutions) with excellent stability for effective overall water ...
Xinjuan Liu   +13 more
wiley   +1 more source

A mini-review of noble-metal-free electrocatalysts for overall water splitting in non-alkaline electrolytes

open access: yesMaterials Reports: Energy, 2021
Development of noble-metal-free materials with remarkable electrocatalytic water-splitting performance in acidic or neutral media has sparked considerable attention in recent years.
Jie Yu   +5 more
doaj   +1 more source

Optoelectronic Synaptic Devices Using Molecular Telluride Phase‐Change Inks for Three‐Factor Learning

open access: yesAdvanced Functional Materials, EarlyView.
Optoelectronic synaptic devices based on solution‐processed molecular telluride GST‐225 phase‐change inks are demonstrated for three‐factor learning. A global optical signal broadcast through a silicon waveguide induces non‐volatile conductance updates exclusively in locally electrically flagged memristors.
Kevin Portner   +14 more
wiley   +1 more source

Insights into the band gap anomalies of certain bismuth-based chalcogenides through ab initio calculations of structural and electronic properties

open access: yesResults in Physics
Unlike other conventional metal chalcogenides, where the Perdew-Burke-Ernzerhof (PBE) functional tends to underestimate band gaps, bismuth (Bi) chalcogenides, particularly Bi selenides, exhibit a counterintuitive behaviour with band gap predictions that ...
Simeon A. Abolade   +4 more
doaj   +1 more source

Shining Light on Anion-Mixed Nanocatalysts for Efficient Water Electrolysis: Fundamentals, Progress, and Perspectives

open access: yesNano-Micro Letters, 2022
Highlights This review introduces recent advances of various anion-mixed transition metal compounds (e.g., nitrides, halides, phosphides, chalcogenides, (oxy)hydroxides, and borides) for efficient water electrolysis applications in detail. The challenges
Yaoda Liu   +5 more
doaj   +1 more source

Solution‐Processed Two‐Dimensional Indium Oxide on Sodium‐Embedded Alumina for Reconfigurable Optoelectronic Synaptic Transistors

open access: yesAdvanced Functional Materials, EarlyView.
Wafer‐scale two‐dimensioanl In2Se3 oxidized into InOx on sodium‐embedded beta‐alumina enables multifunctional reconfigurable electronics. Sodium ions accumulate within distinct spatial distribution under drain‐controlle and gate‐controlled operation. Drain‐control operation gives controllability of ultraviolet‐driven optoelectronic synaptic conductance
Jinhong Min   +13 more
wiley   +1 more source

A new catalytic merit for prediction catalytic potential of 2D materials in LiO2 batteries: Theoretical investigation and experimental identification

open access: yesJournal of Materiomics
Two-dimensional (2D) materials such as metal chalcogenides have great potential as cathode catalyst materials for lithium oxygen batteries (LOBs) due to their large specific surface area and stable chemical properties.
Geng Cheng   +7 more
doaj   +1 more source

Self-surface charge exfoliation and electrostatically coordinated 2D hetero-layered hybrids

open access: yesNature Communications, 2017
Synthesis of atomically thin 2D hetero-layered structures remains a challenge. Here, the authors report a scalable approach to fabricating 2D hetero-layered metal chalcogenides of various compositions: self-surface charge exfoliation, followed by ...
Min-Quan Yang   +6 more
doaj   +1 more source

Chiral Phase Change Nanomaterials

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates reversible, non‐volatile phase transitions in chiral Ge2${\rm Ge}_2$Sb2${\rm Sb}_2$Te5${\rm Te}_5$ (GST) nanohelices for high‐speed optical modulation of chirality and dynamic control of the state of polarization (SOP). The chiral nanostructures are fabricated using a highly directional, wafer‐scale physical vapor deposition ...
Joshua A. Burrow   +11 more
wiley   +1 more source

Interlayer Expansion of Bulk MoS2 via Top‐Down Organic Pillaring Enables Tunable Li+ Intercalation and Controlled Solvent Co‐Intercalation

open access: yesAdvanced Functional Materials, EarlyView.
Top‐down organic pillaring expands the interlayer spacing of bulk‐sized MoS2 particles while preserving the bulk morphology. Operando X‐ray diffraction and electrochemical dilatometry show that MoS2‐bulk undergoes solvent co‐intercalation in diglyme electrolyte, causing large structural expansion, while pillared, expanded MoS2 suppresses solvent uptake
Jaehoon Choi   +8 more
wiley   +1 more source

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