Metal-Hydride C-C Cross-Coupling of Alkenes Through a Double Outer-Sphere Mechanism. [PDF]
J Org ChemDao N, Gan XC, Shenvi RA.
europepmc +1 more source
Asymmetric Reduction of Unactivated Alkenes
Chemistry – A European Journal, EarlyView.Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner +3 more
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Effects of Hydrogen Dissociation During Gas Flooding on Formation of Metal Hydride Cluster Ions in Secondary Ion Mass Spectrometry. [PDF]
Nanomaterials (Basel)Ekar J +4 more
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Hydrogen mobility in the lightest reversible metal hydride, LiBeH3. [PDF]
Sci Rep, 2017 Mamontov E +3 more
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Planar Chirality Controls Diastereotopicity in [2.2]Paracyclophanyl Cyclopropenes
Chemistry – A European Journal, EarlyView.In this work, we report the synthesis of [2.2]paracyclophane‐substituted cyclopropenes via rhodium‐catalyzed cyclopropenation using a pCp‐derived carbene precursor. The planar chiral framework induces diastereotopic differentiation of otherwise equivalent alkyl substituents, which is reflected in their 1H NMR spectra.
Tilman Köhler +3 more
wiley +1 more source
Processing and Characterization of Spent Nickel-Metal Hydride Type AA Batteries to Recover Valuable Materials (Cobalt, Nickel and Rare Earth Elements). [PDF]
Materials (Basel)Iacob G +4 more
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Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane. [PDF]
J Am Chem Soc, 2018 Tanushi A, Radosevich AT.
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Unlocking Heterobimetallic Architectures in a Symmetric PNNP Ligand Environment
Chemistry – A European Journal, EarlyView.A symmetric PNNP ligand enables the modular assembly of heterobimetallic ZnRu and CoRu complexes from a mononuclear Ru(II) precursor. Ligand deprotonation triggers dearomatization and contraction of the metal–metal distance. Combined DFT and QTAIM analyses reveal metallophilic interaction in CoRu but not in ZnRu, highlighting controllable geometric and
Stanislav Melnikov +4 more
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Hydrogen-absorbing alloy-based metal-hydride actuation for application in rehabilitative systems. [PDF]
Technol Health Care, 2018 Kim K, Kim SH, Kim SH, Yu CH.
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Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst
Chemistry – A European Journal, EarlyView.While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival +9 more
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