Results 151 to 160 of about 35,023 (278)

It's a Gas: Bioconjugation With Vapor‐Phase Reagents

open access: yesChemistry – A European Journal, EarlyView.
Gaseous reagents are an emerging class of bioconjugation reagents that can offer alternative selectivity paradigms for the construction of precise bioconjugates. A variety of both inert and highly reactive gases have recently been developed for bioconjugation use.
Yuxuan Ding, Jun Ohata, Zachary T. Ball
wiley   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich   +9 more
wiley   +1 more source

Asymmetric Reduction of Unactivated Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner   +3 more
wiley   +1 more source

Propane dehydrogenation catalysis of group IIIB and IVB metal hydrides. [PDF]

open access: yesRSC Adv
Hu X   +10 more
europepmc   +1 more source

Using Additives to Control the Decomposition Temperature of Sodium Borohydride [PDF]

open access: yes, 2020
Jubert Tomasso, Camille   +3 more
core  

Planar Chirality Controls Diastereotopicity in [2.2]Paracyclophanyl Cyclopropenes

open access: yesChemistry – A European Journal, EarlyView.
In this work, we report the synthesis of [2.2]paracyclophane‐substituted cyclopropenes via rhodium‐catalyzed cyclopropenation using a pCp‐derived carbene precursor. The planar chiral framework induces diastereotopic differentiation of otherwise equivalent alkyl substituents, which is reflected in their 1H NMR spectra.
Tilman Köhler   +3 more
wiley   +1 more source

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