Results 151 to 160 of about 2,813,429 (292)

Synthesis of Dithienylcycloalkene Molecular Switches Enabled by a Bench‐Stable Ti‐Complex

Chemistry – A European Journal, EarlyView.
Herein we report a set of cycloalkene‐bridged DTEs with ring sizes ranging from 4‐ to 7‐membered rings. The synthesis of these analogs was performed via a key McMurry coupling step, which was enabled by a practical, bench‐stable Ti(IV)‐complex. Remarkably, it is shown that the strained cyclobutene bridge outperforms other rings, even the most commonly ...
Marcell M. Bogner, Márton Hegedűs, Péter P. Kalapos, Attila Kunfi, Gábor London   +4 more
wiley   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

Chemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Regio‐ and Diastereoselective C–C Silylation of Cyclopropyl Acetates Harnessing Fluorinated Poly(pyridyl)Borate Rhodium Catalysts

Chemistry – A European Journal, EarlyView.
Fluorinated poly(pyridyl)borates have been utilized to stabilize rhodium‐diene complexes and as supporting ligands in rhodium‐catalyzed redox‐neutral C–C silylation of cyclopropyl acetates, producing silicon‐containing heterocyclic products, dioxasilolanes.
Vo Quang Huy Phan, Suman Das Adhikary, Junha Jeon, H. V. Rasika Dias   +3 more
wiley   +1 more source

Simple s-block metal hydrides for selective hydrogenation of quinoline compounds. [PDF]

Chem Sci
Zhang S, Wen H, Wang Q, Cai Y, Li Z, Liu L, Chang X, Guo J, Chen P.   +8 more
europepmc   +1 more source

Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization. [PDF]

Chem Sci, 2020
Salvadori E, Chiesa M, Buonerba A, Grassi A.   +3 more
europepmc   +1 more source

Mononuclear Molybdenum and Tungsten Phosphine Complexes for Catalytic Ammonia Synthesis: Development of the pentaPod Concept

ChemPhysChem, EarlyView.
The pentaPod (P5) concept unites tridentate and tripodal fragments to form molybdenum and tungsten catalytic Chatt‐type complexes for N2‐to‐NH3 reduction. Two pentaPod ligands, P5Me and P5Pln, are available with either two dimethylphosphine or phospholano (Pln) groups. The complexes enable the investigation of reactivity differences in N2 reduction and,
Anna‐Marlene Vogt, Tobias Adrian Engesser, Jan Krahmer, Felix Tuczek   +3 more
wiley   +1 more source

Physically interpretable descriptors drive the materials design of metal hydrides for hydrogen storage. [PDF]

Chem Sci
Jang SH, Zhang D, Tran HB, Jia X, Konno K, Sato R, Orimo SI, Li H.   +7 more
europepmc   +1 more source

Na₃FeH₇ and Na₃CoH₆: Hydrogen-Rich First-Row Transition Metal Hydrides from High Pressure Synthesis. [PDF]

Inorg Chem, 2020
Spektor K, Crichton WA, Filippov S, Simak SI, Fischer A, Häussermann U.   +5 more
europepmc   +1 more source

On Distribution of Superconductivity in Metal Hydrides [PDF]

Current opinion in solid state & materials science, 2018
D. Semenok, I. Kruglov, I. A. Savkin, A. Kvashnin, A. Oganov   +4 more
semanticscholar   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source