Results 161 to 170 of about 2,813,429 (292)

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

Using Additives to Control the Decomposition Temperature of Sodium Borohydride [PDF]

open access: yes, 2020
Jubert Tomasso, Camille   +3 more
core  

Engineering a Stable Solid–Electrolyte Interphase through a Novel Trifluoromethyl‐Free Lithium Salt for Lithium Metal Polymer Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The motivation behind the development of the new lithium salt LiDFFSI is to combine the advantages of both LiFSI and LiDFSI salts. LiDFFSI offers high ionic conductivity and enhanced compatibility with aluminum current collectors. Additionally, it promotes the formation of a conductive SEI layer rich in LiF and LiH, which contributes to an extended ...
Lorena García   +9 more
wiley   +1 more source

Sulfur‐Rich μ‐O Diiron Catalyst for Electrochemical Hydrogen Production

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
A diferric μ‐oxido complex supported by a sulfur‐rich scaffold acts as a proton‐reduction electrocatalyst for H2 production via a μ‐hydroxido species. An aminodithiophenolate scaffold with an NS2 donor set supports diiron complex formation. The diferrous precursor activates O2, giving rise to a diferric μ‐oxido species, which acts as a proton‐reduction
Hugo C. Hernández‐Toledo   +7 more
wiley   +1 more source

Recent Developments in the Field of Air‐Stable Nickel(0) Precatalysts for Cross‐Coupling Reactions

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The development of bench‐stable Ni(0) sources aims to replace air‐sensitive [Ni(COD)2] (cod = cycloocta‐1,5‐diene) with easy‐to‐handle alternatives. Through a targeted ligand design, using electron‐deficient dienes, carbenes, and fluorophosphines, researchers have achieved air‐ and moisture‐tolerant complexes that show high catalytic activity in cross ...
Franziska Flecken, Schirin Hanf
wiley   +1 more source

Dinuclear Rhodium(I)–N‐Heterocyclic Carbene Complexes as Alkyne Hydropyridonation Catalysts

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Catalyst Improvement by NHC tuning: A series of new RhI–NHC dinuclear complexes has been revealed as efficient alkyne hydropyridonation catalysts. 333053IMes complex displays the highest reactivity of the series, suggesting that a moderate steric demand combined with balanced σ‐donation facilitates precatalyst activation and substrate exchange.
Belinda Español‐Sánchez   +7 more
wiley   +1 more source

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