Results 191 to 200 of about 2,813,429 (292)

Indole‐Based π‐Extended Monophosphine Ligands for Enhanced Palladium‐Catalyzed Sonogashira Coupling

open access: yesJournal of Heterocyclic Chemistry, EarlyView.
A general palladium‐catalyzed Sonogashira cross‐coupling of (hetero)aryl chlorides with aliphatic, (hetero)aryl alkynes is described using Pd(dba)₂/PCy2‐Napdole‐phos catalyst system. The reaction protocol exhibits broad substrate scope and the catalyst loading can be down to 0.2 mol% Pd.
Yu Kiu Lau   +9 more
wiley   +1 more source

Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO2 Reduction

open access: yes, 2017
Kate M. Waldie   +4 more
semanticscholar   +1 more source

Influence of the Cr to Ti Ratio on the High‐Temperature Oxidation Behavior of TaMoCrTiAl Complex Concentrated Alloys in Nitrogen‐Free Atmospheres

open access: yesMaterials and Corrosion, EarlyView.
Ta‐Mo‐Cr‐Ti‐Al refractory high‐entropy alloys show atmosphere‐dependent oxidation performance based on Cr:Ti ratios. Cr‐rich compositions excel in dry oxygen through continuous chromia formation, while Ti‐rich alloys perform better in humid conditions due to reduced chromium volatilization and hydrogen uptake effects.
Fabian Lanoy   +6 more
wiley   +1 more source

Catechol‐Containing Poly(2‐isopropyl‐2‐oxazoline): Synthesis and Thermoresponsive Behavior in Aqueous Salt Solutions

open access: yesMacromolecular Rapid Communications, EarlyView.
Polymers carrying catechol groups are interesting mussel‐inspired materials for wet adhesion applications or metal ion complexation for wastewater treatment. Here, catechol‐containing poly(2‐isopropyl‐2‐oxazoline)s were synthesized via microwave‐assisted cationic (co)polymerization and examined with regard to their thermoresponsive LCST behavior in ...
Niclas Madaj   +4 more
wiley   +1 more source

Chemical Ionization Mass Spectrometry: Fundamental Principles, Diverse Applications, and the Latest Technological Frontiers

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT The review examines the evolution of chemical ionization mass spectrometry (CI‐MS), a technique developed in 1966 by Field and Munson. CI is a soft‐ionization method that produces more intense molecular ions with less fragmentation than electron ionization (EI).
Malvika Dutt   +4 more
wiley   +1 more source

Systematic First-Principles Study of Binary Metal Hydrides.

open access: yesACS Combinatorial Science, 2017
N. Bourgeois   +3 more
semanticscholar   +1 more source

Metal Hydrides‐Based Hydrogen Purification Systems—A Review

open access: yesMetalMat, EarlyView.
Metal hydrides as an innovative means to purify hydrogen can enable new avenues in the use of hydrogen as a clean energy vector across its production methods. ABSTRACT This review investigates the critical role of purification for enabling the use of hydrogen from various production pathways.
Cameron Reid   +2 more
wiley   +1 more source

Engineering Pd Nanostructures on Hierarchical Flower‐Like Alumina Nanosheets for the Efficient Catalytic Reduction of 4‐Nitrophenol

open access: yesNano Select, EarlyView.
Palladium nanocubes and nanoparticles supported on nanosheet‐assembled alumina (NA‐Al2O3) were investigated as highly efficient catalysts for the reduction of 4‐nitrophenol. Systematic comparisons highlight the roles of nanoparticle morphology and support structure, with PdNC@NA and PdNP@NA showing superior activity and stability over commercial Al2O3 ...
Nihal Chelampetty Para   +2 more
wiley   +1 more source

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