Results 201 to 210 of about 35,023 (278)

The X‐Ray Crystal Structure of BorF, the Flavin Reductase Subunit of a Two‐Component Flavin‐Dependent Tryptophan Halogenase

Proteins: Structure, Function, and Bioinformatics, EarlyView.
ABSTRACT BorF is a short‐chain flavin reductase from a desert soil bacterium that uses NADH to reduce FAD to FADH2, which is used by the tryptophan‐6‐halogenase BorH to chlorinate tryptophan in the biosynthetic pathway of borregomycin A. The X‐ray crystal structure of BorF bound to FAD was solved to 2.37 Å by molecular replacement.
Zheng Ma, Emily W. Rady, Aravinda J. de Silva, John J. Bellizzi III   +3 more
wiley   +1 more source

Enzymatic Metal-Hydrogen Atom Transfer with a Cobalt Protoporphyrin Cofactor. [PDF]

J Am Chem Soc
Masonheimer CL, Rourke MJ, Gardner RS, Hall RL, Perkins LJ, Brunold TC, Buller AR.   +6 more
europepmc   +1 more source

Exploring the Fragmentation of Sodiated Species Involving Covalent‐Bond Cleavages for Metabolite Characterization

Rapid Communications in Mass Spectrometry, EarlyView.
ABSTRACT Rationale Electrospray (ESI), the most popular desorption/ionization technique used in mass spectrometry‐based metabolomics, generates both protonated and deprotonated molecules, as well as adduct ions, sodium being the most frequent monoatomic cation entering their composition.
Annelaure Damont, Ekaterina Darii, Chenqin Cao, Anaïs Legrand, Alain Perret, Sylvain Dechaumet, Amina S. Woods, Christophe Junot, Jean‐Claude Tabet, François Fenaille   +9 more
wiley   +1 more source

Cu₁₄H₁₂(P<i>^t</i>Bu₃)₆Cl₂-The Expanse of Stryker's Reagent. [PDF]

Molecules
Strienz M, Kimmich R, Conzelmann A, Schnepf A.   +3 more
europepmc   +1 more source

Potassium‐Doped Borophane Nanosheets: A Multifunctional Platform for Reversible Hydrogen Storage and Metal‐Free Hydrogen Transfer

Small, EarlyView.
Borophane in dual roles: as a reductant in the conversion of levulinic acid to γ‐valerolactone and as a reversible hydrogen reservoir through partial rehydrogenation. ABSTRACT 2D borophene has long been proposed as a promising hydrogen storage material, but experimental demonstrations remain limited to boron hydride sheets derived from MgB2.
Rajamohanan Sobhana Anju, Pankaj Kumar, Dhanaji R. Naikwadi, Bettina Baumgartner, Savi Chaudhary, Atul Bansode, Merel C. Konings, Freek Ariese, Erdni D. Batyrev, Prasad Gonugunta, Vimal Chandra Srivastava, Ramaswamy Murugavel, N. Raveendran Shiju   +12 more
wiley   +1 more source

Search for thermodynamically stable ambient-pressure superconducting hydrides in the GNoME database. [PDF]

Commun Phys
Sanna A, Cerqueira TFT, Cubuk ED, Errea I, Fang YW.   +4 more
europepmc   +1 more source

Sequential Optimization of Multivariate Metal–Organic Framework Based Biocatalysis

Small, EarlyView.
A sequential Latin hypercube sampling–coupled Bayesian optimization (LHS‐BO) workflow integrates multivariate zirconium‐based metal–organic framework based biocomposite (E‐MOF) design with enzyme biocascade reaction optimization. The optimized E‐MOFs stabilize glucose oxidase and horseradish peroxidase in bioactive conformation, exhibiting high ...
Weibin Liang, Sisi Zheng, Ross Andrew Shalliker, Christian Doonan, Feng Li   +4 more
wiley   +1 more source

Going Deep into the Surface Chemistry of Carbon Dots: Influence of Functional Groups on the Redox Abilities

Small, EarlyView.
The chemical structure of Carbon Dots (CDs) is still a mystery despite years of study. Herein, we show how CDs with a higher density of surface‐accessible amines display enhanced (photo)redox performance. Electrochemical and thermodynamic analyses confirmed the feasibility of electron transfer, while mechanistic investigations revealed that the ...
Laura Morbiato, Maria Sbacchi, Jacopo Dosso, Paolo Pengo, Pierangelo Gobbo, Giacomo Filippini, Maurizio Prato   +6 more
wiley   +1 more source

Self-modulated hydrogen electrocatalysis on sub-2-nm platinum nanoparticles by in situ generated surface hydrides. [PDF]

Nat Commun
Chang L, Shao Y, Miao L, Jiang Y, Lu Q, Wang S, Kang F, Li J, Gan L.   +8 more
europepmc   +1 more source

Transition Metal Hydrides [PDF]

, 1978
openaire   +1 more source