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Structural, Mechanical, Electronic, and Optical Properties of Hydrogen-Storage Magnesium-Based Mg<sub>2</sub>XH<sub>9</sub> (X = Cs, Rb). [PDF]
Materials (Basel)Li W +5 more
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Catalyzed Complex Metal Hydrides
MRS Bulletin, 2002AbstractComplex hydrides are mixed ionic–covalent compounds that can serve as reversible H2storage media only when they are catalyzed by a transition metal such as Ti. As the prime example, the phenomenology of Ti-catalyzed sodium alanate (NaAlH4) is reviewed from a historical perspective.
Bogdanović, B., Sandrock, G.
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ChemPhysChem, 2008
AbstractThe goal of the medieval alchemist, the chemical transformation of common metals into nobel metals, will forever be a dream. However, key characteristics of metals, such as their electronic band structure and, consequently, their electric, magnetic and optical properties, can be tailored by controlled hydrogen doping.
Arndt, Remhof, Andreas, Borgschulte
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AbstractThe goal of the medieval alchemist, the chemical transformation of common metals into nobel metals, will forever be a dream. However, key characteristics of metals, such as their electronic band structure and, consequently, their electric, magnetic and optical properties, can be tailored by controlled hydrogen doping.
Arndt, Remhof, Andreas, Borgschulte
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From Metal Hydrides to Metal Borohydrides
Inorganic Chemistry, 2018Commencing from metal hydrides, versatile synthesis, purification, and desolvation approaches are presented for a wide range of metal borohydrides and their solvates. An optimized and generalized synthesis method is provided for 11 different metal borohydrides, M(BH4) n, (M = Li, Na, Mg, Ca, Sr, Ba, Y, Nd, Sm, Gd, Yb), providing controlled access to ...
Bo Richter +4 more
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SECONDARY BATTERIES – NICKEL SYSTEMS | Nickel–Metal Hydride: Metal Hydrides
2009Many scientists and even policy-makers are nowadays openly speculating about the future hydrogen economy for which it is believed that hydrogen-driven fuel cells are going to play a dominant role in transportation, thereby replacing conventional and inefficient internal combustion engines.
P.H.L. Notten, M. Latroche
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Rhodium Tetracarbonyl Hydride: The Elusive Metal Carbonyl Hydride
Angewandte Chemie International Edition, 200210.1002/1521-3773(20021018)41:203.0.CO;2-0 ; Angewandte Chemie - International Edition ; 41 ; 20 ; 3785-3789 ...
Li, C. +3 more
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Journal of the American Chemical Society, 1998
Hydride transfer from neutral transition metal hydrides (MH) to Ph3C+BF4- gives M-FBF3 and Ph3CH. The rate law −d[Ph3C+BF4-]/dt = k[Ph3C+BF4-][MH] was established from kinetic measurements using stopped-flow methods. Second-order rate constants determined in CH2Cl2 solution at 25 °C range from kH− = 7.2 × 10-1 M-1 s-1 to kH− = 4.6 × 106 M-1 s-1.
Tan-Yun Cheng +2 more
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Hydride transfer from neutral transition metal hydrides (MH) to Ph3C+BF4- gives M-FBF3 and Ph3CH. The rate law −d[Ph3C+BF4-]/dt = k[Ph3C+BF4-][MH] was established from kinetic measurements using stopped-flow methods. Second-order rate constants determined in CH2Cl2 solution at 25 °C range from kH− = 7.2 × 10-1 M-1 s-1 to kH− = 4.6 × 106 M-1 s-1.
Tan-Yun Cheng +2 more
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Nanocrystalline metal hydrides
Journal of Alloys and Compounds, 1997Nanocrystalline hydrides are a new class of material in which outstanding hydrogen sorption may be obtained by proper engineering of the microstructure and surface. In this paper the thermodynamics and kinetics of hydride formation in a nanocrystalline alloy are presented.
L Zaluski, A Zaluska, J.O Ström-Olsen
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International Journal of Hydrogen Energy, 1988
Abstract Ten years of development work in the area of metal hydride technology mean that it is now possible to manufacture hydride facilities for the storage of hydrogen to a high standard of safety both for mobile and for stationary applications. In the case of high-purity hydrogen users in particular, hydride technology offers a real alternative ...
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Abstract Ten years of development work in the area of metal hydride technology mean that it is now possible to manufacture hydride facilities for the storage of hydrogen to a high standard of safety both for mobile and for stationary applications. In the case of high-purity hydrogen users in particular, hydride technology offers a real alternative ...
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