Results 81 to 90 of about 34,898 (144)

Enzymatic Metal-Hydrogen Atom Transfer with a Cobalt Protoporphyrin Cofactor. [PDF]

open access: yesJ Am Chem Soc
Masonheimer CL   +6 more
europepmc   +1 more source

Preferential Reduction of 2-Phenylpyridine under D<sub>2</sub>: Palladium Nanoparticles Stabilized by <i>N</i>-Heterocyclic Carbenes Prefer D<sub>2</sub> to H<sub>2</sub>. [PDF]

open access: yesNano Lett
Suárez-Riaño O   +11 more
europepmc   +1 more source
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Metal Hydride Vibrations: The Trans Effect of the Hydride

Inorganic Chemistry, 2019
trans-Dihydride complexes are important in many homogeneous catalytic processes. Here vibrational spectroscopy and density functional theory (DFT) methods are used for the first time to reveal that 4d and 5d metals transmit more effectively than the 3d metals influence of the ligand trans to the hydride and also couple the motions of the trans-hydrides
David Schnieders   +6 more
openaire   +2 more sources

From Metal Hydrides to Metal Borohydrides

Inorganic Chemistry, 2018
Commencing from metal hydrides, versatile synthesis, purification, and desolvation approaches are presented for a wide range of metal borohydrides and their solvates. An optimized and generalized synthesis method is provided for 11 different metal borohydrides, M(BH4) n, (M = Li, Na, Mg, Ca, Sr, Ba, Y, Nd, Sm, Gd, Yb), providing controlled access to ...
Bo Richter   +4 more
openaire   +4 more sources

Light metal hydrides and complex hydrides for hydrogen storage

Chem. Commun., 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Schüth, F.   +2 more
openaire   +3 more sources

Photoemission and x-ray studies of metal hydrides and hydride formation at metal/hydride interfaces

Solid State Communications, 1985
Abstract Synchrotron radiation photoemission was used to investigate the concentration dependent intensity of hydrogen-induced states for a series of niobium hydrides. These intensities were found to be linearly related to the fraction of β phase hydride present in the sample, as deduced from the bulk phase diagram, and we conclude that fracturing ...
R.A. Butera   +3 more
openaire   +1 more source

Hydride Transfer Reactions of Transition Metal Hydrides:  Kinetic Hydricity of Metal Carbonyl Hydrides

Journal of the American Chemical Society, 1998
Hydride transfer from neutral transition metal hydrides (MH) to Ph3C+BF4- gives M-FBF3 and Ph3CH. The rate law −d[Ph3C+BF4-]/dt = k[Ph3C+BF4-][MH] was established from kinetic measurements using stopped-flow methods. Second-order rate constants determined in CH2Cl2 solution at 25 °C range from kH− = 7.2 × 10-1 M-1 s-1 to kH− = 4.6 × 106 M-1 s-1.
Tan-Yun Cheng   +2 more
openaire   +1 more source

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