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Parabolic oxidation of metals to metal deficit oxides
Oxidation of Metals, 1969A stepwise mechanism is outlined for diffusion-controlled oxidation of a metal Me to a metal deficit oxide Me3−zO, where z is the normal valence of Me in Me3−zO and may equal either 1 or 2. Specifically, oxidation is postulated to occur by (1) chemisorption of a singly ionized oxygen atom O− on the oxide surface with the concomitant formation of an ...
D. W. Bridges, W. M. Fassell
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Oxidation on Metal Oxide Surfaces
1968The redn. of transition metal oxides and of SnO2 + Sb2O3 by 1-butene and butadiene was investigated. A single parameter Qo, defined as the heat necessary to dissociate 0.5 O2 from the oxide, detd. the type of reaction. Starting from Q0 = 17 (MnO2) and proceeding to Q0 = 70 (SnO2), the redn. produces; CO2 -> (oxygenated products) -> butadiene ->
Simons, T.G.J. +3 more
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Proceedings of the IEEE, 2012
In this paper, recent progress of binary metal-oxide resistive switching random access memory (RRAM) is reviewed. The physical mechanism, material properties, and electrical characteristics of a variety of binary metal-oxide RRAM are discussed, with a focus on the use of RRAM for nonvolatile memory application.
H.-S. Philip Wong +8 more
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In this paper, recent progress of binary metal-oxide resistive switching random access memory (RRAM) is reviewed. The physical mechanism, material properties, and electrical characteristics of a variety of binary metal-oxide RRAM are discussed, with a focus on the use of RRAM for nonvolatile memory application.
H.-S. Philip Wong +8 more
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Science, 2017
Catalysis The hydrogenation of carbon dioxide is a key step in the industrial production of methanol. Catalysts made from copper (Cu) and zinc oxide (ZnO) on alumina supports are often used. However, the actual active sites for this reaction—Zn-Cu bimetallic sites or ZnO-Cu interfacial sites—are debated. Kattel et al.
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Catalysis The hydrogenation of carbon dioxide is a key step in the industrial production of methanol. Catalysts made from copper (Cu) and zinc oxide (ZnO) on alumina supports are often used. However, the actual active sites for this reaction—Zn-Cu bimetallic sites or ZnO-Cu interfacial sites—are debated. Kattel et al.
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Synthesis of Superconducting Oxides and Oxide/Metal Composites by Oxidation of Metallic Precursors
MRS Proceedings, 1987ABSTRACTOne method for the synthesis of superconducting oxides is high temperature oxidation of a metallic alloy (a metallic precursor) that contains the metallic constituents of the oxide. In addition, a noble metal can be added to the precursor such that, after oxidation, a two phase, finely divided oxide/metal composite results.
Gregory J. Yurek +2 more
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Comments on ?parabolic oxidation of metals to metal deficit oxides?
Oxidation of Metals, 1972Two fundamental errors are pointed out in a recent paper by Bridges and Fassell Jr1. Both concern the application of the law of mass action to a heterogeneous equilibrium, the first in the case of the sorption equilibrium, the second for the external interfacial reaction.
P. Sarrazin, J. Besson
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Oxidative Stretching of Metal–Metal Bonds to Their Limits
Inorganic Chemistry, 2014Oxidation of quadruply bonded Cr2(dpa)4, Mo2(dpa)4, MoW(dpa)4, and W2(dpa)4 (dpa = 2,2'-dipyridylamido) with 2 equiv of silver(I) triflate or ferrocenium triflate results in the formation of the two-electron-oxidized products [Cr2(dpa)4](2+) (1), [Mo2(dpa)4](2+) (2), [MoW(dpa)4](2+) (3), and [W2(dpa)4](2+) (4).
W. Brogden, David +7 more
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Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals
Chemical Reviews, 2022Jonathan De Roo +2 more
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Single-Atom Catalysts Based on the Metal–Oxide Interaction
Chemical Reviews, 2020Botao Qiao, Zhang Tao, Yike Huang
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