Bis(cobaltocenium) tetrachloridocobaltate(II) dichloromethane 1.2-solvate
IUCrData, 2018 The structure of bis(cobaltocenium) tetrachloridocobaltate(II) dichloromethane 1.2-solvate, [Co(C5H5)2]2[CoCl4]·1.2CH2Cl2, has been determined at 100 K. The title compound crystallizes in the space group P\overline{1} and is an example of an unusual Z′ =
Michael J. Shaw +5 more
doaj +1 more source
Harvesting and Electron-Exchange Energy Transfer by d0 Metallocene-based Organized Systems [PDF]
, 2013 The present contribution will provide an up-to-date overview of novel experimental and theoretical (de-rived quantum-chemically) knowledge on photonics of group IV metallocene-based systems, also with re-spect to their prominent use in catalysis and ...
Loukova, G.V.
core
An Overview of the Potential of UV Modification of Polypropylene [PDF]
, 2016 This is the peer reviewed version of the following article: Amintowlieh, Y., Tzoganakis, C., & Penlidis, A. (2016). An Overview of the Potential of UV Modification of Polypropylene.
Amintowlieh, Yasaman +2 more
core +1 more source
Dibora[2]ferrocenophane: a carbene-stabilized diborene in a strained cis-configuration [PDF]
, 2016 Unsaturated bridges that link the two cyclopentadienyl ligands together in strained ansa metallocenes are rare and limited to carbon-carbon double bonds. The synthesis and isolation of a strained ferrocenophane containing an unsaturated two-boron bridge,
Braunschweig, Holger +9 more
core +1 more source
Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries [PDF]
, 2016 Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state.
Cooke, Graeme +5 more
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Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: precatalysts for propylene polymerization and oligomerization [PDF]
, 2008 Zirconium and titanium complexes with tridentate bis(phenolate)-donor (donor = pyridine, furan and thiophene) ligands have been prepared and investigated for applications in propylene polymerization.
Agapie, Theodor +4 more
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Catalytic N_2-to-NH_3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET [PDF]
, 2017 We have recently reported on several Fe catalysts for N_2-to-NH_3 conversion that operate at low temperature (−78 °C) and atmospheric pressure while relying on a very strong reductant (KC_8) and acid ([H(OEt_2)_2][BArF_4]). Here we show that our original
Chalkley, Matthew J. +4 more
core +1 more source
Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts [PDF]
, 2009 Bisphenolate ligands with pyridine- and benzene-diyl linkers have been synthesized and metalated with group 4 and 5 transition metals. The solid-state structures of some of the group 4 complexes have been solved.
Bercaw, John E., Golisz, Suzanne R.
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An Evaluation of Dilution Rheology for the Characterization of Long Chain Branching of Polyethylenes
Applied Rheology, 2006 The purpose of this paper was to re-evaluate the novel rheological method of Crosby et al. [J. Rheol. 46 (2002) 401] to characterise long chain branching (LCB) in polyethylenes (PE) using the rheology of concentrated solutions.
Chai Choon K., Ang Swe Chong
doaj +1 more source
Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring pK_a Effects and Demonstrating Electrocatalysis [PDF]
, 2018 Substrate selectivity in reductive multi-electron/proton catalysis with small molecules such as N_2, CO_2, and O_2 is a major challenge for catalyst design, especially where the competing hydrogen evolution reaction (HER) is thermodynamically and ...
Chalkley, Matthew J. +3 more
core +1 more source