Results 101 to 110 of about 13,033 (225)

An Overview of the Potential of UV Modification of Polypropylene [PDF]

open access: yes, 2016
This is the peer reviewed version of the following article: Amintowlieh, Y., Tzoganakis, C., & Penlidis, A. (2016). An Overview of the Potential of UV Modification of Polypropylene.
Amintowlieh, Yasaman   +2 more
core   +1 more source

The ethene polymerisation behaviour of zirconium metallocenes: A steric and electronic investigation into the influence of substituent effects [PDF]

open access: yes, 2006
PhD - Biochemistry There are 9 files which have been withheld at the author's requestA systematic investigation into the effect that alkyl and aryl substituents have on the ethene polymerisation behaviour of a series of MAO co-catalysed mono ...
Grimmer, Neil Eugene
core  

An improved method of moments as a more reliable alternative for prediction of average molecular weights of irreversible non-linear polymerizations and reversible polycondensations [PDF]

open access: yes, 2004
An improved method of moments as a more reliable alternative for prediction of average molecular weights of irreversible non-linear polymerizations and reversible ...
Costa, Mário Rui, Dias, Rolando
core  

Estudo da preparação do catalisador Cp2ZrCl2 suportado em sílica utilizando um planejamento de experimentos Preparation conditions of Cp2ZrCl2 supported on silica using an experimental planning

open access: yesPolímeros, 2001
O monômero eteno foi polimerizado através dos sistemas catalíticos Cp2ZrCl2/SiO2 e Cp2ZrCl2/MAO/SiO2. Foi elaborado um planejamento estatístico de experimentos a fim de se identificar as melhores condições de preparo dos catalisadores heterogêneos.
Anunciata Conte   +1 more
doaj   +1 more source

Catalytic N_2-to-NH_3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET [PDF]

open access: yes, 2017
We have recently reported on several Fe catalysts for N_2-to-NH_3 conversion that operate at low temperature (−78 °C) and atmospheric pressure while relying on a very strong reductant (KC_8) and acid ([H(OEt_2)_2][BArF_4]). Here we show that our original
Chalkley, Matthew J.   +4 more
core   +1 more source

Metallocene Hydrides: Their Didactic Value for Teaching Organometallic Chemistry

open access: yesCHIMIA
Metallocene hydrides, Cp2MHn (n=1-3), are complexes known for elements of Groups 3 to 8. Their properties can be understood by the use of a common qualitative MO diagram.
Antonio Togni
doaj   +1 more source

An Evaluation of Dilution Rheology for the Characterization of Long Chain Branching of Polyethylenes

open access: yesApplied Rheology, 2006
The purpose of this paper was to re-evaluate the novel rheological method of Crosby et al. [J. Rheol. 46 (2002) 401] to characterise long chain branching (LCB) in polyethylenes (PE) using the rheology of concentrated solutions.
Chai Choon K., Ang Swe Chong
doaj   +1 more source

Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring pK_a Effects and Demonstrating Electrocatalysis [PDF]

open access: yes, 2018
Substrate selectivity in reductive multi-electron/proton catalysis with small molecules such as N_2, CO_2, and O_2 is a major challenge for catalyst design, especially where the competing hydrogen evolution reaction (HER) is thermodynamically and ...
Chalkley, Matthew J.   +3 more
core   +1 more source

Tensile properties of polyproylene fibres [PDF]

open access: yes, 2009
As soon as it appeared on the market, one half century ago, polypropylene (PP) appeared as a promising fibre-forming polymer but with some difficulties in processing due to a lack of control of its viscoelastic properties and in durability due to its low
FAYOLLE, Bruno   +2 more
core   +2 more sources

Recent progresses in the development of more reliable predictions of average molecular weights and chain-lenght distributions for complex irreversible non-linear polymerizations [PDF]

open access: yes, 2005
Prediction of the structure of branched polymers is a challenging problem, for which only more or less clumsy mathematical solutions have been made available for a long time in the case of kinetically controlled polymerizations.
Costa, Mário Rui, Dias, Rolando
core  

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