Results 21 to 30 of about 902,813 (269)

UHMWPE/SBA-15 nanocomposites synthesized by in situ polymerization [PDF]

open access: yes, 2016
Different nanocomposites have been attained by in situ polymerization based on ultra-high molecular weight polyethylene (UHMWPE) and mesoporous SBA-15, this silica being used for immobilization of the FI catalyst bis [N-(3-tert-butylsalicylidene)-2,3,4,
Adewole   +60 more
core   +3 more sources

Temperature-Dependent Growth of 36 Inner Nanotubes inside Nickelocene, Cobaltocene and Ferrocene-Filled Single-Walled Carbon Nanotubes

open access: yesNanomaterials, 2021
We have investigated the effects of temperature, diameter and metal catalyst type on the growth of inner nanotubes inside metallocene-filled single-walled carbon nanotubes (SWCNTs).
Marianna V. Kharlamova   +1 more
doaj   +1 more source

Gas phase polymerization of ethylene with a silica-supported metallocene catalyst: influence of temperature on deactivation [PDF]

open access: yes, 1997
Ethylene was polymerized at 5 bar in a stirred powder bed reactor with silica supported rac-Me2Si[Ind]2ZrCl2/methylaluminoxane (MAO) at temperatures between 40°C and 80°C using NaCl as support bed and triethylaluminium (TEA) as a scavenger for impurities.
Meier, G.B.   +5 more
core   +2 more sources

The influence of the oxygen donor capacity of polystearylmethacrylate over polyethylene bulk density when using modified methylaluminoxane as co-catalyst [PDF]

open access: yesPolyolefins Journal, 2022
In this work, the interaction between a polystearylmethacrylate (Mn = 8,900 g mol-1, Xn = 26, Ð = 1.1) and modified methylaluminoxane 12 (MMAO-12) co-catalyst is studied using different spectroscopic methods.
Odilia Pérez-Camacho   +1 more
doaj   +1 more source

Chemical and Physical State of Catalysts in the Growth of Single-Walled Carbon Nanotubes inside Metallocene-Filled Single-Walled Carbon Nanotubes

open access: yesMaterials Proceedings, 2023
In this study, the state of catalysts is revealed during the growth of single-walled carbon nanotubes (SWCNTs) inside metallocene-filled SWCNTs. High-resolution transmission electron microscopy and Raman spectroscopy were used to study the kinetics of ...
Marianna V. Kharlamova
doaj   +1 more source

Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates [PDF]

open access: yes, 2014
The catalyst systems (FI)TiCl₃/MAO (FI = phenoxyimine ligand with an additional aryl–O–CH₃ donor) display exceptionally high activity in selective ethylene trimerization.
Bryliakov, Konstantin P.   +8 more
core   +1 more source

Interplay of reversible chain transfer and comonomer incorporation reactions in coordination copolymerization of ethylene/1–hexene [PDF]

open access: yesPolyolefins Journal, 2019
Coordinative chain transfer polymerization (CCTP) has opened a new path for the development of novel products like olefin block copolymers and chain-end functional polyolefins.
Ali Ebrahimi   +4 more
doaj   +1 more source

An Integrated AHP-PROMETHEE Method for Selecting the most Suitable Ethylene Propylene Diene Termonomer [PDF]

open access: yesJournal of Petroleum Science and Technology, 2016
This paper considers the problem of selecting the most appropriate ethylene propylene diene monomer (EPDM), which is a polyolefin with a variety of usages in different areas.
Ali Sibevei   +3 more
doaj   +1 more source

A new post-metallocene-ti catalyst with maltolate bidentade ligand: an investigation in heterogeneous polymerization reactions in different mesoporous supports [PDF]

open access: yes, 2016
A new titanium catalyst easily synthesized from ethylmaltol bidentate chelator ligand was studied in homogeneous and heterogeneous ethylene polymerization.
Basso, Nara Regina de Souza   +6 more
core   +1 more source

Analysis of the Continuous Feeding of Catalyst Particles during the Growth of Vertically Aligned Carbon Nanotubes by Aerosol-Assisted CCVD

open access: yesNanomaterials, 2022
Aerosol-assisted catalytic chemical vapor deposition (AACCVD) is a powerful one-step process to produce vertically aligned carbon nanotubes (VACNTs), characterized by the continuous supply of the catalyst precursor (metallocene). The behavior of catalyst
Celia Castro   +5 more
doaj   +1 more source

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