UHMWPE/SBA-15 nanocomposites synthesized by in situ polymerization [PDF]
Different nanocomposites have been attained by in situ polymerization based on ultra-high molecular weight polyethylene (UHMWPE) and mesoporous SBA-15, this silica being used for immobilization of the FI catalyst bis [N-(3-tert-butylsalicylidene)-2,3,4,
Adewole +60 more
core +3 more sources
We have investigated the effects of temperature, diameter and metal catalyst type on the growth of inner nanotubes inside metallocene-filled single-walled carbon nanotubes (SWCNTs).
Marianna V. Kharlamova +1 more
doaj +1 more source
Gas phase polymerization of ethylene with a silica-supported metallocene catalyst: influence of temperature on deactivation [PDF]
Ethylene was polymerized at 5 bar in a stirred powder bed reactor with silica supported rac-Me2Si[Ind]2ZrCl2/methylaluminoxane (MAO) at temperatures between 40°C and 80°C using NaCl as support bed and triethylaluminium (TEA) as a scavenger for impurities.
Meier, G.B. +5 more
core +2 more sources
The influence of the oxygen donor capacity of polystearylmethacrylate over polyethylene bulk density when using modified methylaluminoxane as co-catalyst [PDF]
In this work, the interaction between a polystearylmethacrylate (Mn = 8,900 g mol-1, Xn = 26, Ð = 1.1) and modified methylaluminoxane 12 (MMAO-12) co-catalyst is studied using different spectroscopic methods.
Odilia Pérez-Camacho +1 more
doaj +1 more source
In this study, the state of catalysts is revealed during the growth of single-walled carbon nanotubes (SWCNTs) inside metallocene-filled SWCNTs. High-resolution transmission electron microscopy and Raman spectroscopy were used to study the kinetics of ...
Marianna V. Kharlamova
doaj +1 more source
Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates [PDF]
The catalyst systems (FI)TiCl₃/MAO (FI = phenoxyimine ligand with an additional aryl–O–CH₃ donor) display exceptionally high activity in selective ethylene trimerization.
Bryliakov, Konstantin P. +8 more
core +1 more source
Interplay of reversible chain transfer and comonomer incorporation reactions in coordination copolymerization of ethylene/1–hexene [PDF]
Coordinative chain transfer polymerization (CCTP) has opened a new path for the development of novel products like olefin block copolymers and chain-end functional polyolefins.
Ali Ebrahimi +4 more
doaj +1 more source
An Integrated AHP-PROMETHEE Method for Selecting the most Suitable Ethylene Propylene Diene Termonomer [PDF]
This paper considers the problem of selecting the most appropriate ethylene propylene diene monomer (EPDM), which is a polyolefin with a variety of usages in different areas.
Ali Sibevei +3 more
doaj +1 more source
A new post-metallocene-ti catalyst with maltolate bidentade ligand: an investigation in heterogeneous polymerization reactions in different mesoporous supports [PDF]
A new titanium catalyst easily synthesized from ethylmaltol bidentate chelator ligand was studied in homogeneous and heterogeneous ethylene polymerization.
Basso, Nara Regina de Souza +6 more
core +1 more source
Aerosol-assisted catalytic chemical vapor deposition (AACCVD) is a powerful one-step process to produce vertically aligned carbon nanotubes (VACNTs), characterized by the continuous supply of the catalyst precursor (metallocene). The behavior of catalyst
Celia Castro +5 more
doaj +1 more source

