Results 141 to 150 of about 4,711,558 (216)

Pyridinium Cations Act as Charge Reservoirs in Expanded Halide Perovskite Analogs at High Pressure

Angewandte Chemie, EarlyView.
Redox‐innocent pyridinium derivatives can act as charge reservoirs in expanded tin‐iodide perovskite analogs. Material compression reduces the energy gap between the pyridinium π* acceptor orbital and the valence‐band maximum, facilitating electron transfer from the framework to the molecules and thereby significantly increasing electronic conductivity
Christina R. Deschene, Feng Ke, Kostas Fykouras, Alexander C. Su, Yu Lin, Linn Leppert, Hemamala I. Karunadasa, Roc Matheu   +7 more
wiley   +2 more sources

Reconstructing Solvation Structure via Strongly Nucleophilic Anions for High‐Rate and Low‐Temperature Graphite||LFP Pouch Cells in PC‐Based Electrolyte

Advanced Energy Materials, EarlyView.
A nucleophilic‐anion‐regulated solvation strategy is developed for Propylene carbonate (PC)‐based electrolytes, where NO3−${\mathrm{NO}}_3^ - $ preferentially enters the Li+ solvation sheath and replaces coordinated PC molecules without sacrificing ionic conductivity.
Dichang Guan, Wenting Jia, Yue Fei, Zhiyuan Xue, Huan Ni, Guorong Hu, Zhongdong Peng, Yanbing Cao, Jian Wang, Qiang Liu, Ke Du, Ge Li   +11 more
wiley   +1 more source

Vacuum‐Induced Surface Reconstruction of Mn–Ce Oxides for Low‐Temperature Coupled Redox Catalysis

Angewandte Chemie, EarlyView.
Near‐surface reconstruction enhances low‐temperature redox catalysis in Mn–Ce mixed oxides. Sequential vacuum annealing and reduced‐pressure O2 treatment enrich Mn near the surface while preserving the CeO2 fluorite framework, promoting interfacial electron redistribution, oxygen activation, and redox cycling.
Yong Yin, Yide Jiang, Zichen Xu, Min Liu, Emiliano Cortés, Yifei Sun   +5 more
wiley   +2 more sources

Reveal Non‐Uniform Passivation on Lithium Metal Anode With Operando Spectroscopic Ellipsometry

Advanced Energy Materials, EarlyView.
In‐operando spectroscopic ellipsometry reveals how nucleation and crystallographic orientation govern the non‐uniform growth of native passivation films on lithium metal. Time‐resolved thickness mapping captures island formation and coalescence, while orientation‐dependent measurements show that the equilibrium film on Li(110) is approximately half as ...
Jianyu Li, Hanrui Zhang, Dongliang Chen, Feifei Shi   +3 more
wiley   +1 more source

Explaining the Origin of Negative Poisson's Ratio in Amorphous Networks With Machine Learning

Advanced Intelligent Discovery, EarlyView.
This review summarizes how machine learning (ML) breaks the “vicious cycle” in designing auxetic amorphous networks. By transitioning from traditional “black‐box” optimization to an interpretable “AI‐Physics” closed‐loop paradigm, ML is shown to not only discover highly optimized structures—such as all‐convex polygon networks—but also unveil hidden ...
Shengyu Lu, Xiangying Shen
wiley   +1 more source

A Comprehensive Comparative Study of Active Learning Schemes for Nanophotonics Design

Advanced Intelligent Discovery, EarlyView.
Active learning (AL) strategies are benchmarked for the binary design of planar multilayer nanophotonic structures. Factorization machines combined with quantum annealing (QA) become effective as dimensionality increases. Hybrid QA provides the strongest results for 100‐layer problems, highlighting the importance of optimization method selection in ...
Serang Jung, Seongmin Kim, Jaehyun Park, Chaeyoung Park, Zhihao Xu, Sanghyo Hwang, Baiqing Ye, Youn sang Kim, Sun‐Kyung Kim, Tengfei Luo, Eungkyu Lee   +10 more
wiley   +1 more source

Design and Characterization of a Dual‐Mode Soft Robotic Flapping Propeller With Pneumatic Stiffness Modulation

Advanced Intelligent Systems, EarlyView.
A novel soft robotic propeller overcomes traditional efficiency‐flexibility tradeoffs via a hybrid pneumatic‐cable actuation strategy. This architecture enables active stiffness modulation with dual‐mode locomotion: tunable biomimetic swimming and earthworm‐inspired wriggling for confined spaces.
Jiazi Geng, Hua Shao, Yiyang Li, Lin Liang, Jinfeng Yang, Xianhong He, Fengran Xie   +6 more
wiley   +1 more source

Short Sb···Sb Contacts in Polymorphic Tris(p‐Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid‐State Chemistry?

Angewandte Chemie International Edition, EarlyView.
Discovery of polymorphism in solid tris(p‐tolyl)antimony(III) highlighted short, direct antimony‐antimony contacts, with interatomic separation shorter than the sum of the van der Waals radii, and calculated interaction energy of ca. 26 kJ mol−1 that includes a significant dispersion component.
Imogen Suh, Michael Ferguson, Filip Topić, Fu‐Qiang Gong, Mihails Arhangelskis, Hatem M. Titi, D. Scott Bohle, Vinko Nemec, Levente Kiss, Andrew J. Morris, Cristian Silvestru, Dominik Cinčić, Tomislav Friščić   +12 more
wiley   +1 more source

Advancements in CO2 Capture Technologies: A Review of Amine Absorption and Alternative Methods for Post‐Combustion Integration

Asia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Carbon capture technologies are poised to become one of the primary focuses regarding the achievement of net‐zero emissions by the year 2050. In these technologies, particular attention is given to post‐combustion CO2 capture, which is more easily implemented at existing power stations and other industries.
Satyajit Mukherjee, Ashish Kumar, Mayurkumar P. Patil, Rohit B. Meshram   +3 more
wiley   +1 more source

Numerical Study of MHD Hybrid Nanofluid Flow With Multiple Slip Effects Over a Variable Porous Stretching Surface

Asia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT This work discusses the thermal performance of magnetized hybrid nanofluid flow over a variable porous stretchable surface, emphasizing the underlying physical mechanisms governing heat and mass transfer. The Cattaneo–Christov flux model is used in place of Fourier's and Fick's laws to incorporate relaxation effects, ensuring a more realistic ...
Mounirah Areshi, Abdul Bariq, Salemah A. Almutlak, Fahad Maqbul Alamrani, Zehba Raizah, Anwar Saeed   +5 more
wiley   +1 more source