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Methane Hydration‐Shell Structure and Fragility
AbstractThe influence of oily molecules on the structure of liquid water is a question of importance to biology and geology and many other fields. Previous experimental, theoretical, and simulation studies of methane in liquid water have reached widely conflicting conclusions regarding the structure of hydrophobic hydration‐shells.
Xiangen Wu +4 more
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Methane hydrate stability and anthropogenic climate change [PDF]
Methane frozen into hydrate makes up a large reservoir of potentially volatile carbon below the sea floor and associated with permafrost soils. This reservoir intuitively seems precarious, because hydrate ice floats in water, and melts at Earth surface ...
D. Archer
doaj
Destabilization of intrapermafrost gas hydrates is one of the possible mechanisms responsible for methane emission in the Arctic shelf. Intrapermafrost gas hydrates may be coeval to permafrost: they originated during regression and subsequent cooling and
Evgeny Chuvilin +5 more
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Gas hydrates in sub-seabed sediments is an unexploited source of energy with estimated reserves larger than those of conventional oil. One of the methods for recovering methane from gas hydrates involves injection of Carbon Dioxide (CO2), causing the ...
Luís Bernardes +4 more
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This study explores the production of hydrates with binary (CH4/C2H6) gaseous mixtures, varying the concentration of each species from 25 to 75 vol%. The thermodynamics of this process are explored in detail, and the achieved results are explained in ...
Alberto Maria Gambelli +3 more
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Data-driven discovery of methane hydrate promoters
Methane hydrates require extreme conditions, and promoter discovery remains largely empirical. We develop a multimodal deep-learning framework that predicts methane-hydrate equilibrium pressures from molecular structure. Trained on over eighty promoters,
Yusung Ok, Youngjune Park
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Distinct creep regimes of methane hydrates predicted by a monatomic water model
The power-law creep properties of methane hydrates were measured experimentally two decades ago, but their microscopic explanation is still missing. Here we show, using molecular dynamics simulations spanning almost 2 orders of magnitude of stresses and ...
Henrik Andersen Sveinsson, Pinqiang Cao
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The low permeability of the methane hydrate-bearing sediment limits the methane gas extraction. To enhance methane hydrate extraction, hydraulic fracturing can be a promising approach to improve the hydrate reservoir permeability by creating a fracture ...
Hao Sun, Xiangyu Xu, Chao Jia
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Dissociation and Self-Preservation of Gas Hydrates in Permafrost
Gases releasing from shallow permafrost above 150 m may contain methane produced by the dissociation of pore metastable gas hydrates, which can exist in permafrost due to self-preservation.
Evgeny Chuvilin +4 more
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Methane hydrate stability in seawater
Experimental data are presented for methane hydrate stability conditions in seawater (S ≈ 33.5‰). For the pressure range of 2.75–10.0 MPa, at any given pressure, the dissociation temperature of mcthane hydrate is depressed by approximately −1.1°C relative to the pure methane‐pure water system.
Gerald R. Dickens, Mary S. Quinby‐Hunt
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