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HYDRATES OF METHANE AND HYDROGEN
2019Gas hydrates are icelike solids composed of guest molecules or atoms of gases trapped inside the cages formed within a crystalline host framework (clathrate) of hydrogenbonded water molecules. The report will mainly be devoted to various aspects of the formation and decomposition of methane hydrates, large deposits of which are found in permafrost and ...
Antonov, V.E. +4 more
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Phase Diagram of Methane Hydrates and Discovery of MH-VI Hydrate
The Journal of Physical Chemistry A, 2018Methane hydrate is not only the predominant natural deposits of permafrost and continental margins of Earth but also the dominant methane-containing phase in the nebula and major moons of gas giants. Depending on the surrounding environment (mainly pressure), seven methane hydrate phases have been discovered by experiment or predicted by computer ...
Yingying Huang +5 more
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Numerical Simulation of Methane Production from a Methane Hydrate Formation
Industrial & Engineering Chemistry Research, 2008This paper describes a one-dimensional model for hydrate dissociation in porous media by the depressurization method. A moving boundary, which separates the total simulation zone into two zones, is used. The governing equations consider the convective-conductive heat transfer and mass transfer in the gas and hydrate zones together with the energy ...
LIU Y, STRUMENDO, MATTEO, ARASTOOPOUR H.
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Recovering Methane from Solid Methane Hydrate with Carbon Dioxide
Angewandte Chemie, 2003CO2 in, CH4 out! From NMR spectroscopic measurements of composition and kinetics, it can be shown that the recovery of methane from methane hydrate is possible through its reaction with CO2 (see diagram), even though the yield is less than that expected from kinetic and thermodynamic arguments.
Lee H +4 more
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Photocatalytic conversion of methane contained in methane hydrates
Topics in Catalysis, 2005Photocatalytic conversion of methane dissolved in water at 1 MPa and 100 MPa, and methane contained in methane hydrates was performed. Several photocatalysts based on tungsten oxide and titania was investigated. Both full spectrum and visible light were used as the illumination source.
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Sea Floor Methane Hydrates at Hydrate Ridge, Cascadia Margin
2013The crest of Hydrate Ridge harbors a variety of gas hydrates in near-surface sediments. Hydrate formation and destruction continuously shape the ridge topography. Interstitial Cl-anomaly patterns in conjunction with video-guided sampling have established that the uppermost sediment column contains several distinct layers of gas hydrate which are ...
Suess, E. +19 more
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Energy, 2020
Abstract Most of the existing experimental and theoretical studies concern the combustion of methane hydrate. There are no works comparing the features and differences of combustion of different types of gas hydrates. In addition, there is a lack of data on the comparison of different combustion methods.
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Abstract Most of the existing experimental and theoretical studies concern the combustion of methane hydrate. There are no works comparing the features and differences of combustion of different types of gas hydrates. In addition, there is a lack of data on the comparison of different combustion methods.
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Simulations of the methane hydrate/methane gas interface near hydrate forming conditions conditions
Fluid Phase Equilibria, 1996Abstract Molecular dynamics simulations have been used to probe the interface between type I methane hydrate and methane gas in the temperature range 250–300 K, and at pressures of 1 and 100 MPa. The interface was found to be stable up to 270 K, with the onset of melting occurring more readily at the lower pressure.
P.M. Rodger, T.R. Forester, W. Smith
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Contrasting the hydration thermodynamics of methane and methanol
Physical Chemistry Chemical Physics, 2019The hydration thermodynamics of methane and methanol depend on the cavity creation work and energy of van der Waals and H-bonding attractions.
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Kinetics of methane hydrate dissociation
Doklady Physical Chemistry, 2015The methane hydrate dissociation at an external pressure of 1 bar has been experimentally studied. The methane dissociation rate depends on the heat transfer intensity in the course of dissociation. Quasi-isothermal and nonisothermal conditions of clathrate dissociation have been compared.
V. E. Nakoryakov, S. Ya. Misyura
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