Results 121 to 130 of about 162,868 (272)

Photocatalytic Asymmetric C‐C Coupling for CO2 Reduction on Cu‐Zn Bimetallic Catalysts with Dipole‐Limiting Effects

Advanced Science, EarlyView.
Asymmetric Cu–Zn dual sites on EDTA‐grafted Ti‐MOF amplify the dipole‐limiting domain field (DLDF), facilitating C–C coupling. This strategy yields an exceptional C2H4 production rate of 308.72 µmol g−1 h−1 with 98.4% electron selectivity in photocatalytic CO2 reduction, highlighting the potential of asymmetric site engineering and local field ...
Peidong Ma, Ying Yu, Fan Wen, Hongyan Guo, Boyu Li, GuoZhi Deng, Xianyang Shi, Daochuan Jiang, Ruting Huang   +8 more
wiley   +1 more source

Non‐Equilibrium Synthesis Methods to Create Metastable and High‐Entropy Nanomaterials

Advanced Science, EarlyView.
ABSTRACT Stabilizing multiple elements within a single phase enables the creation of advanced materials with exceptional properties arising from their complex composition. However, under equilibrium conditions, the Hume–Rothery rules impose strict limitations on solid‐state miscibility, restricting combinations of elements with mismatched crystal ...
Shuo Liu, Chaochao Dun, Jeffrey J. Urban, Mark T. Swihart   +3 more
wiley   +1 more source

Experimental realization of catalytic CH_4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability [PDF]

, 2009
A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO_4 and KIO_3 gives the oxy ...
Ess, Daniel H., Goddard, William A., III, Meier, Steven K., Oxgaard, Jonas, Periana, Roy A., Stewart, Timothy, Young, Kenneth J. H.   +6 more
core   +1 more source

Combining Electrochemical Reduction with Biosynthesis for Directed Conversion of CO2 into a Library of C3 Chemicals

Advanced Science, EarlyView.
In the H‐type electrolytic cell, carbon dioxide is reduced to acetic acid via electro‐microbial catalysis. The simply processed acetic acid is further converted through biological fermentation into high‐value‐added products, including acrylic acid, L‐lactic acid, and β‐alanine.
Kaixing Xiao, Shanquan Liang, Xujun Zhao, Zhiyao Peng, Ruoshi Luo, Jikai Zong, Ling Zhou, Yude Su, Dan Wang   +8 more
wiley   +1 more source

Conjugation effects in ethane oxidation under the conditions of oxidative coupling of methane

Тонкие химические технологии, 2014
Ethane conversion under the conditions of oxidative coupling of methane (OCM) has been investigated. In an empty reactor above 800°C, ethane oxidation occurs at a higher rate, and its main product is carbon monoxide.
V. I. Lomonosov, T. R. Usmanov, M. Yu. Sinev, S. N. Antonyuk   +3 more
doaj  

Basal Plane Activation of SnS2 Thin‐Film by Fluorine Doping for Selective Solar‐Driven CO2 Reduction With Enhanced Quantum Efficiency

Advanced Science, EarlyView.
The synergistic effect of fluorine doping and sulfur vacancies boosts the activity of the active sites without active‐site modulation, leading to enhanced CO2 photoreduction efficiency and a selectivity switch from CH4 to CO on tin disulfide continuous thin films. ABSTRACT Photocatalytic conversion of CO2 into value‐added fuels offers a viable approach
Tadios Tesfaye Mamo, Mohammad Qorbani, Adane Gebresilassie Hailemariam, Putikam Raghunath, Che‐Men Chu, Wen‐Hsin Yuan, Amr Sabbah, Yen‐Yu Wang, Shuo‐Yun Chang, Ming‐Chang Lin, Wei‐Yen Woon, Yu‐Jung Lu, Heng‐Liang Wu, Ken‐Tsung Wong, Kuei‐Hsien Chen, Li‐Chyong Chen   +15 more
wiley   +1 more source

Estimation of advective methane flux in gas hydrate potential area offshore SW Taiwan and its tectonic implications [PDF]

, 2011
With the discoveries of Bottom Simulating Reflectors (BSRs), large and dense chemosynthetic communities and rapid sulfate reductions in pore space sediments, gas hydrates may exist in offshore southwestern Taiwan.
Chuang, Pei-Chuan, Chung, San-Hsiung, Dale, Andy W., Lin, Saulwood, Wallmann, Klaus, Wang, Yunshuen, Yang, Tsanyao Frank   +6 more
core  

Efficient and Robust Heterostructure CeZrOx/NiO‐Ni Inverse Catalyst for Sustainable Photothermal CO2 Methanation

Advanced Science, EarlyView.
A heterostructured CeZrOx/NiO‐Ni inverse catalyst is designed for highly efficient photothermal CO2 methanation under low‐intensity light without auxiliary heating. It achieves 464 mmol·gcat−1·h−1 methane space‐time yield under natural concentrated sunlight, maintains stability over light‐dark cycles and extended air storage, and is scalable to 100 g ...
Chuqiao Song, Zhaohua Wang, Zhouhong Ren, Cheng Yu, Haibo Li, Xin Tang, Houhong Song, Yao Xu, Liangwei Liu, Lili Han, Liwei Chen, Zhifu Qi, Xi Liu, Siyu Yao, Xiao‐nian Li, Xiang Gao, Lili Lin   +16 more
wiley   +1 more source

Shallow and deep groundwater moderate methane dynamics in a high Arctic glacial catchment

Frontiers in Earth Science
Glacial groundwater can mobilize deep-seated methane from beneath glaciers and permafrost in the Arctic, leading to atmospheric emissions of this greenhouse gas.
Gabrielle E. Kleber, Gabrielle E. Kleber, Gabrielle E. Kleber, Leonard Magerl, Alexandra V. Turchyn, Kelly Redeker, Stefan Thiele, Martin Liira, Martin Liira, Koit Herodes, Lise Øvreås, Andrew Hodson, Andrew Hodson   +12 more
doaj   +1 more source

Vapor‐Assisted Catalysis Enables Precise Construction of MOF‐Derived Hierarchical Carbon Nanoarrays for High‐Performance Supercapacitors

Advanced Science, EarlyView.
A remote‐control strategy for catalyst design is unveiled for advanced carbon materials. During pyrolysis, zinc vapor from a physically separate source guides cobalt catalysts to construct a hierarchical carbon nanoarray. This approach prevents structural collapse while directing the dense growth of carbon nanotubes, yielding a material with ...
Xiaoyang Deng, Zihao Wan, Huan Xin, Xiaoguang Wang, Wenjuan Wang, Feixiong Chen, Liying Ma, Naiqin Zhao   +7 more
wiley   +1 more source