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Quasicrystalline Catalyst for Steam-Reforming of Methanol

MRS Proceedings, 2000
AbstractSteam reforming of methanol (CH3OH + H2O -> 3H2 + CO2) has been performed on a number of Al-Cu-based stable quasicrystals and related alloys. Alloys leached in NaOH aqueous solution exhibit the highest activity for steam-reforming of methanol. Among the alloys, AlCuFe quasicrystal, after leaching treatment, reveals excellent activity.
A.P. Tsai, M. Yoshimura
openaire   +1 more source

Integrated Methanol Steam Reformer/Electrochemical Hydrogen Compressor

ECS Transactions, 2013
An electrochemical hydrogen compressor (EHC) based on a solid acid electrolyte is built. The EHC operates at temperatures from 230 to 250 °C. The EHC can be used to separate hydrogen from simulated reformate containing more than 2 % CO. The EHC can be directly combined with a methanol steam reformer (MSR).
Ru Chen   +4 more
openaire   +1 more source

Controlling ZnO morphology for improved methanol steam reforming reactivity

Physical Chemistry Chemical Physics, 2008
The selectivity towards CO2 during steam reforming of methanol on Pd increases in the order Al2O3 < ZrO2 < ZnO. However, conventional catalyst preparation can damage the ZnO surface, even causing complete dissolution. The faceted, prismatic ZnO crystals in the support (Aldrich) get easily destroyed during catalyst preparation. We show in this work that,
Ayman M, Karim   +2 more
openaire   +2 more sources

Methanol steam reforming over ex-hydrotalcite Cu–Zn–Al catalysts

Applied Catalysis A: General, 2006
Cu-ZnO-Al2O3 catalysts have been prepared via hydrotalcite-like hydroxycarbonate precursors and tested in the oxidative steam reforming of methanol (MOSR) to produce hydrogen with poor CO content. The surface chemistry of the catalysts has been investigated by IR spectroscopy of low temperature CO adsorption.
BUSCA, GUIDO   +6 more
openaire   +3 more sources

Steam reforming of methanol using supported Mo2C catalysts

Applied Catalysis A: General, 2007
Abstract Two supported molybdenum carbide catalysts, Mo2C supported on γ-alumina (Mo2C/γ-Al2O3) and zirconia (Mo2C/ZrO2), were investigated as an alternative catalyst for steam reforming of methanol. The catalysts were prepared by a temperature-programmed reaction (TPR) method, and it was found that the supported Mo2C catalysts are superior to an ...
Sean S.-Y. Lin   +3 more
openaire   +1 more source

Development of Methanol Steam Reformer for Chemical Recuperation

Journal of Engineering for Gas Turbines and Power, 2000
The purpose of the present work is to establish the design method of methanol steam-reformer for application to chemical recuperation in a gas turbine system. The reaction rate of the methanol steam-reforming was measured with a small amount of catalyst using the gaseous mixture of methanol, water, hydrogen, and carbon dioxide as a simulated product ...
T. Nakagaki   +3 more
openaire   +1 more source

Steam Reforming of Methanol Over Pd-Zn Catalysts

Reaction Kinetics and Catalysis Letters, 2000
Heating the physical mixtures of Pd and Zn selectively yielded PdZn or Pd3.9Zn6.1 alloy. These alloys were highly selective for the steam reforming of methanol.
Nobuhiro Iwasa   +3 more
openaire   +1 more source

Microwave-activated methanol steam reforming for hydrogen production

International Journal of Hydrogen Energy, 2011
Abstract Methanol steam reforming (MSR) was carried out in a catalytic packed bed reactor under electrical and microwave heating using the two most common catalysts for this process–CuZnO/Al 2 O 3 and PdZnO/Al 2 O 3 . Significant two-dimensional temperature gradients were found, especially in the latter case.
Tomasz Durka   +3 more
openaire   +1 more source

ZnPd in Methanol Steam Reforming

Zeitschrift für anorganische und allgemeine Chemie, 2012
Armbrüster, M., Friedrich, M., Luo, Y.
openaire   +2 more sources

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