Results 131 to 140 of about 607,889 (218)

Photometallobiocatalytic Asymmetric Radical‐Mediated Cross‐Coupling of Organotrifluoroborate Salts and Pyridotriazoles

open access: yesAngewandte Chemie, EarlyView.
An enantioselective photometallobiocatalytic cross‐coupling of pyridotriazoles and secondary alkyltrifluoroborate salts is developed. Cooperative catalysis using eosin B and an engineered protoglobin combines visible‐light‐mediated radical generation with enzymatic metal carbenoid activation, affording valuable N‐heterocyclic products in excellent ...
Huanan Wang   +5 more
wiley   +2 more sources

Supramolecular Mechanophore Additives Enable Mechanochromic Hydrogels

open access: yesAngewandte Chemie, EarlyView.
A supramolecular loop‐forming mechanophore featuring a quencher and an emitter is incorporated as a water‐soluble macromolecular additive into hydrogels. In the stress‐free state, intramolecular charge‐transfer interactions fold the loop and quench fluorescence.
Iulia Scarlat   +2 more
wiley   +2 more sources

Unexplained high and persistent methyl bromide emissions in China. [PDF]

open access: yesNat Commun
Hu X   +7 more
europepmc   +1 more source

1,4‐Brook Rearrangement of β‐Silyl Allylic Alcohols: Trisubstituted Alkenes by Copper‐Mediated Stereoretentive ipso‐Substitution Reactions

open access: yesAngewandte Chemie, EarlyView.
To fully leverage the power of the ruthenium‐catalyzed trans‐hydrosilylation of propargyl alcohols, it was necessary to develop a practical and robust method for the activation of those products that carry the silyl group distal to the hydroxy substituent.
Paul Haf‐Moths   +2 more
wiley   +2 more sources

Disentangling conical intersection and coherent molecular dynamics in methyl bromide with attosecond transient absorption spectroscopy. [PDF]

open access: yesNat Commun, 2019
Timmers H   +9 more
europepmc   +1 more source

Influence of Substitution on the Interplay of Photochemical Switching and Phase Transitions in Azobenzene‐Based Molecular Materials

open access: yesAngewandte Chemie, EarlyView.
This study investigates the influence of several substituents at different positions on photochemical and thermal properties of azobenzene‐based materials to provide valuable structure‐property relationships for the specific design of azobenzene‐based materials for future energy storage and phase change materials. ABSTRACT Understanding and translating
Conrad Averdunk, Hermann A. Wegner
wiley   +2 more sources

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