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Benchmark thermodynamic analysis of methylammonium lead iodide decomposition from first principles
Hybrid organic–inorganic perovskites (HOIPs) such as methylammonium lead iodide (MAPbI _3 ) are promising candidates for use in photovoltaic cells and other semiconductor applications, but their limited chemical stability poses obstacles to their ...
Douglas Heine, Hui-Chia Yu, Volker Blum
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This work reported the successive incorporation of tetrabutylammonium (TBA) into Methylammonium lead Iodide (MAPbI3) perovskite. The thin films were characterized by X-Ray diffraction (XRD), Scanning electron microscopy (SEM), Transmittance electron ...
Amal Bouich +5 more
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The electrochemical stability of 22 commercially available hydrophobic ionic liquids was measured at different temperatures (288.15, 298.15, 313.15, 333.15 and 358.15 K), to systematically investigate ionic liquids towards electrolytes for ...
Kallidanthiyil Chellappan Lethesh +4 more
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Role of Water on the Rotational Dynamics of the Organic Methylammonium Cation: A First Principles Analysis [PDF]
AbstractUnderstanding the degradation mechanisms of lead-halide perovskites (CH3NH3PbI3) under exposure to liquid/aerosol water is an essential problem within the photovoltaic community. Herein we investigate both the static and the dynamic properties of the methylammonuim cation (MA) as it coordinates with invading water molecules (MA.(H2O)n, n = 1, 2,
Hoehn, Ross D. +3 more
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Sodium faujasite zeolites with Si/Al ratio of 1.4 and 2.5 were exchanged with methylammonium cations. The influence of framework aluminum and ion exchange degree in their basic properties were evaluated.
Karina Arruda Almeida +1 more
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In light of the intense recent interest in the methylammonium lead halides, CH3NH3PbX3 (X = Cl, Br, and I) as sensitizers for photovoltaic cells, the dynamics of the methylammonium (MA) cation in these perovskite salts has been reinvestigated as a function of temperature via 2H, 14N, and 207Pb NMR spectroscopy.
Guy M. Bernard +6 more
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Organic Cation Rotation and Immobilization in Pure and Mixed Methylammonium Lead-Halide Perovskites [PDF]
Three-dimensional lead-halide perovskites have attracted a lot of attention due to their ability to combine solution processing with outstanding optoelectronic properties. Despite their soft ionic nature these materials demonstrate a surprisingly low level of electronic disorder resulting in sharp band edges and narrow distributions of the electronic ...
Oleg Selig +8 more
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Methylammonium antimony sulfide [PDF]
Bis(methylammonium) octaantimony(III) dodecasulfide persulfide, (CH3NH3)(2)[Sb8S12(S-2)], contains pairs of [Sb4S7](2-) chains joined through an unusual persulfide bond to create infinite double [Sb8S14](2-) chains.
Powell, A.V. +8 more
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The promise of hybrid organic–inorganic halide perovskite solar cells rests on their exceptional power conversion efficiency routinely exceeding 25% in laboratory scale devices.
Daniele T. Cuzzupè +9 more
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Hybrid Organic–Inorganic Perovskite Superstructures for Ultrapure Green Emissions
All inorganic CsPbBr3 superstructures (SSs) have attracted much research interest due to their unique photophysical properties, such as their large emission red-shifts and super-radiant burst emissions.
Wen Kiat Chan +9 more
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